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• W2896415986 abstract "The ring opening reaction of diosgenin acetate in presence of Lewis acids and trimethylsilyl azide was explored as a facile approach to the synthesis of an open chain derivative with a nitrogen-containing substituent at C26. The reaction, under optimal conditions (TMSOTf, 1 equiv.; TMSN3, 1.1 equiv.; DCM; 48 h; rt), provided satisfactory yield (40%) of furostane-26-nitrile in a single step." @default.
• W2896415986 created "2018-10-26" @default.
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• W2896415986 date "2019-07-01" @default.
• W2896415986 modified "2023-09-24" @default.
• W2896415986 title "Study on the reaction of diosgenin acetate with trimethylsilylazide catalyzed by Lewis acids" @default.
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• W2896415986 doi "https://doi.org/10.1016/j.steroids.2018.10.007" @default.
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