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• W2896416237 abstract "Abstract In this study, UCl 4 was prepared by the reaction of HCl gas with UO 2 in the LiCl-KCl eutectic. Then, the electrochemical behavior of U 4+ and U 3+ on a Mo cathode was investigated by various electrochemical techniques. The reduction process of U 4+ was regarded as two steps: U 4+ +e=U 3+ ; U 3+ +3e=U. Diffusion coefficients of U 4+ and U 3+ , the apparent standard potential of U 4+ /U 3+ , U 3+ /U as well as U 4+ /U in the LiCl-KCl molten salt on the Mo electrode was determined by numerous electrochemical methods. The thermodynamic functions of formation of Gibbs free energy of UCl 4 and UCl 3 are calculated as well." @default.
• W2896416237 created "2018-10-26" @default.
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• W2896416237 date "2018-10-13" @default.
• W2896416237 modified "2023-09-25" @default.
• W2896416237 title "Electrochemical and thermodynamic properties of U⁴⁺and U³⁺on Mo electrode in LiCl-KCl eutectic" @default.
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• W2896416237 doi "https://doi.org/10.1515/ract-2017-2898" @default.
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