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- W2896421604 endingPage "14843" @default.
- W2896421604 startingPage "14836" @default.
- W2896421604 abstract "Alkyl chlorides are common functional groups in synthetic organic chemistry. However, the engagement of unactivated alkyl chlorides, especially tertiary alkyl chlorides, in transition-metal-catalyzed C-C bond formation remains challenging. Herein, we describe the development of a TiIII-catalyzed radical addition of 2° and 3° alkyl chlorides to electron-deficient alkenes. Mechanistic data are consistent with inner-sphere activation of the C-Cl bond featuring TiIII-mediated Cl atom abstraction. Evidence suggests that the active TiIII catalyst is generated from the TiIV precursor in a Lewis-acid-assisted electron transfer process." @default.
- W2896421604 created "2018-10-26" @default.
- W2896421604 creator A5002353006 @default.
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- W2896421604 creator A5044877276 @default.
- W2896421604 creator A5056497816 @default.
- W2896421604 creator A5069060254 @default.
- W2896421604 date "2018-10-10" @default.
- W2896421604 modified "2023-10-16" @default.
- W2896421604 title "Ti-Catalyzed Radical Alkylation of Secondary and Tertiary Alkyl Chlorides Using Michael Acceptors" @default.
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- W2896421604 doi "https://doi.org/10.1021/jacs.8b08605" @default.
- W2896421604 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6530901" @default.
- W2896421604 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30303379" @default.