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• W2896439181 abstract "Tris(2-(arylamido)-4,6-di-tert-butylphenoxo)molybdenum(vi) complexes (Rap)3Mo can be prepared either from (cycloheptatriene)Mo(CO)3 and the N-aryliminoquinone, or from MoO2(acac)2 and the aminophenol. In contrast to all other reported unconstrained transition metal tris(amidophenoxide) complexes, the molybdenum complexes show a facial geometry in the solid state. In solution, the fac isomer predominates, though a small amount of mer isomer is detectable at room temperature. At elevated temperature the two species interconvert through Rây-Dutt trigonal twists, which are faster than Bailar twists in this system, presumably because of steric effects of the N-aryl groups. Substituents on the N-aryl ring shift the fac/mer equilibrium of the complex, with more electron-withdrawing substituents generally increasing the proportion of the mer isomer. The preference for fac over mer geometry is thus suggested to be due to enhanced π bonding in the fac isomer. In contrast to analogous catecholate complexes, the tris(amidophenoxide) complexes are not Lewis acidic and are inert to nucleophilic oxidants such as amine-N-oxides." @default.
• W2896439181 created "2018-10-26" @default.
• W2896439181 creator A5003794117 @default.
• W2896439181 creator A5053820192 @default.
• W2896439181 date "2018-01-01" @default.
• W2896439181 modified "2023-10-10" @default.
• W2896439181 title "Molybdenum(<scp>vi</scp>) tris(amidophenoxide) complexes" @default.
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• W2896439181 doi "https://doi.org/10.1039/c8dt03392g" @default.
• W2896439181 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30346454" @default.
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