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• W2896446246 endingPage "841" @default.
• W2896446246 startingPage "841" @default.
• W2896446246 abstract "Stable polymeric micelles have been demonstrated to serve as suitable templates for creating mesoporous metals. Herein, we report the utilization of a core-shell-corona type triblock copolymer of poly(styrene-b-2-vinylpyridine-b-ethylene oxide) and H₂PtCl₆·H₂O to synthesize large-sized mesoporous Pt particles. After formation of micelles with metal ions, the reduction process has been carried out by vapor infiltration of a reducing agent, 4-(Dimethylamino)benzaldehyde. Following the removal of the pore-directing agent under the optimized temperature, mesoporous Pt particles with an average pore size of 15 nm and surface area of 12.6 m²·g-1 are achieved. More importantly, the resulting mesoporous Pt particles exhibit superior electrocatalytic activity compared to commercially available Pt black." @default.
• W2896446246 created "2018-10-26" @default.
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• W2896446246 date "2018-10-16" @default.
• W2896446246 modified "2023-10-16" @default.
• W2896446246 title "Micelle-Assisted Strategy for the Direct Synthesis of Large-Sized Mesoporous Platinum Catalysts by Vapor Infiltration of a Reducing Agent" @default.
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• W2896446246 doi "https://doi.org/10.3390/nano8100841" @default.
• W2896446246 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6215267" @default.
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• W2896446246 hasPublicationYear "2018" @default.
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