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• W2896500771 abstract "S-heteroarenes containing cyclopenta[ b]thiopyran moieties were synthesized via intramolecular ring-expanding cycloisomerization from 1-acetyl-2-thienyl-substituted precursors catalyzed by PtCl2. In comparison to the other two S-heteroarene isomers experiencing common 6-endo and 5-exo cyclization processes, the aromatic cyclopenta[ b]thiopyran derivative demonstrates intriguing photophysical and electrochemical properties, such as near-infrared absorption, low oxidation potential, and excellent electrochemical stability. Therefore, this work provides an effective pathway to incorporate cyclopenta[ b]thiopyran as building blocks for organic semiconductors with unique properties." @default.
• W2896500771 created "2018-10-26" @default.
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• W2896500771 date "2018-10-22" @default.
• W2896500771 modified "2023-10-17" @default.
• W2896500771 title "From Colorless to Near-Infrared <i>S</i>-Heteroarene Isomers: Unexpected Cycloaromatization of Cyclopenta[<i>b</i>]thiopyran Catalyzed by PtCl₂" @default.
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• W2896500771 doi "https://doi.org/10.1021/acs.orglett.8b02546" @default.
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