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• W2896514303 abstract "A scalable and practical synthesis of functionalized indoles via Pd-tBuONO cocatalyzed aerobic cycloisomerization of o-allylanilines is reported. Using molecular oxygen as a terminal oxidant, a series of substituted indoles were prepared in moderate to good yields. The avoidance of hazardous oxidants, heavy-metal cocatalysts, and high boiling point solvents such as DMF and DMSO enables this method to be applied in pharmaceutical synthesis. A practical gram-scale synthesis of indomethacin demonstrates its application potential." @default.
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• W2896514303 date "2018-10-08" @default.
• W2896514303 modified "2023-10-14" @default.
• W2896514303 title "Synthesis of Functionalized Indoles via Palladium-Catalyzed Aerobic Cycloisomerization of <i>o</i>-Allylanilines Using Organic Redox Cocatalyst" @default.
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• W2896514303 doi "https://doi.org/10.1021/acs.joc.8b01999" @default.
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