Matches in SemOpenAlex for { <https://semopenalex.org/work/W2896528416> ?p ?o ?g. }
- W2896528416 endingPage "14" @default.
- W2896528416 startingPage "7" @default.
- W2896528416 abstract "Abstract Platinum vinylcarbene complexes are potentially useful for organometallic synthesis and catalysis, but have been rarely studied. This work reports a convenient route to make platinum vinylcarbene complexes. Treatment of [PtCl2(PPh3)]2 with propargyl alcohols HC≡CC(OH)RR’ (RR’ = Ph2, cyclo-C6H10(OH), (iPr)(C≡CTMS) and (H)(Ph)) in the presence of EtOH produced the vinylcarbene complexes trans-PtCl2{ = C(OEt)-CH=CRR’}(PPh3). Under similar condition, [PtCl2(PPh3)]2 reacted with HC≡CC(OH)Me2 to give cis-PtCl2{ = C(OEt)-CH=CMe2}(PPh3). Complex trans-PtCl2{ = C(OEt)-CH=CPh2}(PPh3) readily undergo a metathesis reaction with NaI to give trans-PtI2{ = C(OEt)-CH=CPh2}(PPh3) which can isomerize to cis-PtI2{ = C(OEt)-CH=CPh2}(PPh3). Complex trans-PtCl2{ = C(OEt)-CH=CPh2}(PPh3) reacted with PPh3 to give EtCl and the acyl complex trans-PtCl{C(O)CH=CPh2}(PPh3)2, which can undergo a decarbonylation reaction to give PtCl(CH=CPh2)(PPh3)2." @default.
- W2896528416 created "2018-10-26" @default.
- W2896528416 creator A5009145955 @default.
- W2896528416 creator A5025575420 @default.
- W2896528416 creator A5042600687 @default.
- W2896528416 creator A5053577649 @default.
- W2896528416 creator A5088557049 @default.
- W2896528416 date "2019-02-01" @default.
- W2896528416 modified "2023-10-16" @default.
- W2896528416 title "Synthesis and reactivity of platinum vinylcarbene complexes prepared from activation of propargyl alcohols" @default.
- W2896528416 cites W1793259612 @default.
- W2896528416 cites W1920540088 @default.
- W2896528416 cites W1952143115 @default.
- W2896528416 cites W1963811446 @default.
- W2896528416 cites W1964414013 @default.
- W2896528416 cites W1966182479 @default.
- W2896528416 cites W1971287270 @default.
- W2896528416 cites W1972803006 @default.
- W2896528416 cites W1974814437 @default.
- W2896528416 cites W1977375588 @default.
- W2896528416 cites W1982270085 @default.
- W2896528416 cites W1984614201 @default.
- W2896528416 cites W1987097512 @default.
- W2896528416 cites W1989072509 @default.
- W2896528416 cites W1990458028 @default.
- W2896528416 cites W1992451996 @default.
- W2896528416 cites W1995478593 @default.
- W2896528416 cites W1998952966 @default.
- W2896528416 cites W2008596419 @default.
- W2896528416 cites W2009878313 @default.
- W2896528416 cites W2012127104 @default.
- W2896528416 cites W2014623418 @default.
- W2896528416 cites W2019191686 @default.
- W2896528416 cites W2019726210 @default.
- W2896528416 cites W2021427228 @default.
- W2896528416 cites W2022063832 @default.
- W2896528416 cites W2023271753 @default.
- W2896528416 cites W2024866489 @default.
- W2896528416 cites W2026525277 @default.
- W2896528416 cites W2027962987 @default.
- W2896528416 cites W2028842590 @default.
- W2896528416 cites W2035286517 @default.
- W2896528416 cites W2035368959 @default.
- W2896528416 cites W2038096785 @default.
- W2896528416 cites W2044337365 @default.
- W2896528416 cites W2046662458 @default.
- W2896528416 cites W2048414234 @default.
- W2896528416 cites W2049267542 @default.
- W2896528416 cites W2054433914 @default.
- W2896528416 cites W2057594923 @default.
- W2896528416 cites W2059205366 @default.
- W2896528416 cites W2064226638 @default.
- W2896528416 cites W2065165030 @default.
- W2896528416 cites W2066949448 @default.
- W2896528416 cites W2067380736 @default.
- W2896528416 cites W2070559153 @default.
- W2896528416 cites W2082883385 @default.
- W2896528416 cites W2084973301 @default.
- W2896528416 cites W2084990612 @default.
- W2896528416 cites W2090519451 @default.
- W2896528416 cites W2094009189 @default.
- W2896528416 cites W2099258775 @default.
- W2896528416 cites W2100326980 @default.
- W2896528416 cites W2119685186 @default.
- W2896528416 cites W2131350133 @default.
- W2896528416 cites W2137298951 @default.
- W2896528416 cites W2143954497 @default.
- W2896528416 cites W2143981217 @default.
- W2896528416 cites W2149122848 @default.
- W2896528416 cites W2150096349 @default.
- W2896528416 cites W2155842268 @default.
- W2896528416 cites W2160158033 @default.
- W2896528416 cites W2161052700 @default.
- W2896528416 cites W2169263140 @default.
- W2896528416 cites W2175326861 @default.
- W2896528416 cites W2207070880 @default.
- W2896528416 cites W2317279620 @default.
- W2896528416 cites W2320981394 @default.
- W2896528416 cites W2326565776 @default.
- W2896528416 cites W2328826969 @default.
- W2896528416 cites W2329281767 @default.
- W2896528416 cites W2531809639 @default.
- W2896528416 cites W2572764382 @default.
- W2896528416 cites W2754920783 @default.
- W2896528416 cites W2762112707 @default.
- W2896528416 cites W2949445768 @default.
- W2896528416 cites W2952021538 @default.
- W2896528416 cites W2952926356 @default.
- W2896528416 cites W3137537591 @default.
- W2896528416 cites W4234116142 @default.
- W2896528416 cites W4375905943 @default.
- W2896528416 cites W2129183518 @default.
- W2896528416 doi "https://doi.org/10.1016/j.jorganchem.2018.10.016" @default.
- W2896528416 hasPublicationYear "2019" @default.
- W2896528416 type Work @default.
- W2896528416 sameAs 2896528416 @default.
- W2896528416 citedByCount "3" @default.
- W2896528416 countsByYear W28965284162019 @default.