FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2896550494> ?p ?o ?g. }

• W2896550494 endingPage "6928" @default.
• W2896550494 startingPage "6922" @default.
• W2896550494 abstract "Photolysis of α-bromopropiophenones in acetonitrile results in formation of β-bromopropiophenones with good product selectivity, which can be coined as 1,2-Br shift reaction. The product selectivity increases when the reaction is done in neat or solid state, where only the 1,2-Br shift product is formed in some cases. The reaction is suggested to proceed by CBr bond homolysis to give a radical pair, followed by disproportionation and conjugate addition of HBr to the α,β-unsaturated ketone intermediate. When the unsaturated intermediate is stabilized by an extra conjugation, the reaction stops at the stage, in which the unsaturated ketone becomes a major product. The synthetic method described in this research fits in a category of eco-friendly organic synthesis nicely since the reaction does not use volatile organic solvents and any other additives such as acid, base or metal catalysts, etc. Besides, the method fits into perfect atom economy, which does not give any side products. The synthetic method should find much advantage over other alternative methods to obtain β-bromo carbonyl compounds." @default.
• W2896550494 created "2018-10-26" @default.
• W2896550494 creator A5001920193 @default.
• W2896550494 creator A5075549133 @default.
• W2896550494 creator A5086423994 @default.
• W2896550494 date "2018-11-01" @default.
• W2896550494 modified "2023-09-30" @default.
• W2896550494 title "Solvent free, light induced 1,2-bromine shift reaction of α-bromo ketones" @default.
• W2896550494 cites W1794227929 @default.
• W2896550494 cites W1964446724 @default.
• W2896550494 cites W1985066293 @default.
• W2896550494 cites W1988175599 @default.
• W2896550494 cites W1992718976 @default.
• W2896550494 cites W1998676058 @default.
• W2896550494 cites W2003483276 @default.
• W2896550494 cites W2009487701 @default.
• W2896550494 cites W2012757735 @default.
• W2896550494 cites W2014098960 @default.
• W2896550494 cites W2017301726 @default.
• W2896550494 cites W2023678043 @default.
• W2896550494 cites W2026744827 @default.
• W2896550494 cites W2027562725 @default.
• W2896550494 cites W2033218839 @default.
• W2896550494 cites W2041024364 @default.
• W2896550494 cites W2043053031 @default.
• W2896550494 cites W2060725397 @default.
• W2896550494 cites W2065371484 @default.
• W2896550494 cites W2065949020 @default.
• W2896550494 cites W2066848383 @default.
• W2896550494 cites W2074381338 @default.
• W2896550494 cites W2077579252 @default.
• W2896550494 cites W2080347339 @default.
• W2896550494 cites W2085836399 @default.
• W2896550494 cites W2086698625 @default.
• W2896550494 cites W2088526430 @default.
• W2896550494 cites W2095474722 @default.
• W2896550494 cites W2128675326 @default.
• W2896550494 cites W2141546693 @default.
• W2896550494 cites W2161219141 @default.
• W2896550494 cites W2215894026 @default.
• W2896550494 cites W2306086246 @default.
• W2896550494 cites W2313103114 @default.
• W2896550494 cites W2317383270 @default.
• W2896550494 cites W2320028400 @default.
• W2896550494 cites W2322758475 @default.
• W2896550494 cites W2327109699 @default.
• W2896550494 cites W2328169303 @default.
• W2896550494 cites W2334113710 @default.
• W2896550494 cites W2334764440 @default.
• W2896550494 cites W2409008554 @default.
• W2896550494 cites W2409559429 @default.
• W2896550494 cites W2597191578 @default.
• W2896550494 cites W2734515303 @default.
• W2896550494 cites W2939741374 @default.
• W2896550494 cites W2949147502 @default.
• W2896550494 cites W2949874047 @default.
• W2896550494 cites W2951247344 @default.
• W2896550494 cites W2951730734 @default.
• W2896550494 cites W2952361850 @default.
• W2896550494 cites W2953163281 @default.
• W2896550494 cites W2953189008 @default.
• W2896550494 cites W4243307001 @default.
• W2896550494 doi "https://doi.org/10.1016/j.tet.2018.10.015" @default.
• W2896550494 hasPublicationYear "2018" @default.
• W2896550494 type Work @default.
• W2896550494 sameAs 2896550494 @default.
• W2896550494 citedByCount "3" @default.
• W2896550494 countsByYear W28965504942019 @default.
• W2896550494 countsByYear W28965504942021 @default.
• W2896550494 countsByYear W28965504942023 @default.
• W2896550494 crossrefType "journal-article" @default.
• W2896550494 hasAuthorship W2896550494A5001920193 @default.
• W2896550494 hasAuthorship W2896550494A5075549133 @default.
• W2896550494 hasAuthorship W2896550494A5086423994 @default.
• W2896550494 hasConcept C118792377 @default.
• W2896550494 hasConcept C139066938 @default.
• W2896550494 hasConcept C161790260 @default.
• W2896550494 hasConcept C17365422 @default.
• W2896550494 hasConcept C175689099 @default.
• W2896550494 hasConcept C178790620 @default.
• W2896550494 hasConcept C185592680 @default.
• W2896550494 hasConcept C2777463227 @default.
• W2896550494 hasConcept C2777738585 @default.
• W2896550494 hasConcept C2780471494 @default.
• W2896550494 hasConcept C54582936 @default.
• W2896550494 hasConcept C75473681 @default.
• W2896550494 hasConceptScore W2896550494C118792377 @default.
• W2896550494 hasConceptScore W2896550494C139066938 @default.
• W2896550494 hasConceptScore W2896550494C161790260 @default.
• W2896550494 hasConceptScore W2896550494C17365422 @default.
• W2896550494 hasConceptScore W2896550494C175689099 @default.
• W2896550494 hasConceptScore W2896550494C178790620 @default.
• W2896550494 hasConceptScore W2896550494C185592680 @default.
• W2896550494 hasConceptScore W2896550494C2777463227 @default.
• W2896550494 hasConceptScore W2896550494C2777738585 @default.
• W2896550494 hasConceptScore W2896550494C2780471494 @default.
• W2896550494 hasConceptScore W2896550494C54582936 @default.
• W2896550494 hasConceptScore W2896550494C75473681 @default.

• next