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- W2896563263 abstract "Peroxide-induced dynamic vulcanization of poly (vinylidene fluoride)/silicone rubber (PVDF/SR) blends was studied in this paper. We controlled the size of rubber particles by changing the rotor speed, and discussed the influence of shearing on the particle diameter and the particle diameter polydispersity (dp). The size of SR particle was confirmed to be decreased with increasing the rotor speed. However, a good matching degree of shearing and crosslinking rate helped the SR phase to achieve a uniform crosslinking, as well as a narrow dp. In this particular PVDF/SR system, the suitable rotor speed was found to be 90 rpm, at which the dp reached a minimum of 1.1981 and 1.1614 for the P9S1 and the P7S3, respectively. At last, we discussed the influences of the macroscopic breaking energy (Edk) and the coalescence (P) on the number-average particle diameter (Dn) of the SR. This work is thus devoted to construct a model for predicting the particle size in dynamic vulcanization of PVDF/SR blends." @default.
- W2896563263 created "2018-10-26" @default.
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- W2896563263 date "2019-01-01" @default.
- W2896563263 modified "2023-09-23" @default.
- W2896563263 title "Model construction of particle size in dynamic vulcanization of PVDF/SR blends—matching degree between crosslinking and shearing rates" @default.
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- W2896563263 doi "https://doi.org/10.1016/j.matchemphys.2018.10.011" @default.
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