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- W2896583985 abstract "Abstract Four new 1,1′-dialkyl-2,2′-bibenzimidazoles were used to extract zinc(II) from acid chloride solutions at various concentrations of chloride and hydrogen ions. In low acidity media (pH > 2), the maximum zinc(II) extraction with the compounds is observed at chloride concentrations in the range 0.7–1.8 M. Zinc(II) ions are extracted as neutral (ZnCl2)mLn complexes (L = extractant) in which the m:n ratio varies from 1:2 to 3:3, depending on the metal-to-extractant molar ratio in the extraction media. In strongly acidic systems, anionic zinc(II) chloro-complexes may be extracted from aqueous solutions by protonated bibenzimidazoles as (LH+)2(ZnCl42−) or/and (LH+)(ZnCl3−) ion pairs. In weakly acidic media, at [Cl−]" @default.
- W2896583985 created "2018-10-26" @default.
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- W2896583985 date "2018-12-01" @default.
- W2896583985 modified "2023-10-17" @default.
- W2896583985 title "Solvent extraction of zinc from chloride solutions using dialkyl derivatives of 2,2′-bibenzimidazole as extractants" @default.
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- W2896583985 doi "https://doi.org/10.1016/j.hydromet.2018.10.005" @default.
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