FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2896608559> ?p ?o ?g. }

• W2896608559 endingPage "1690" @default.
• W2896608559 startingPage "1683" @default.
• W2896608559 abstract "Abstract The main aim of this study was to describe both the formation process of SiOC glasses doped with Al3+ cations and the resulting differences in their structures in comparison with undoped silicon oxycarbide glasses. A novel material was formed by means of the sol-gel method with the application of alkyl-substituted alkoxysilanes and a butoxy derivative of aluminum (Al(OC4H9)3) as a source of Al3+ ions. After the synthesis of a sol, the material was treated with a two-step thermal processing including aging (70 °C) and annealing (800 °C). As a result, yellowish xerogel (aging) and black glasses (annealing) were obtained and subjected to structural investigation, including X-ray diffraction (XRD), middle infrared spectroscopy (MIR), Raman, electron dispersive spectroscopy (EDS), and nuclear magnetic resonance (NMR) methods. The obtained results were compared to corresponding findings for SiOC glasses, obtained with the same experimental procedure. An additional thermogravimetric analysis (TGA) study was carried out for the xerogel in order to determine its thermal behavior in a protective atmosphere up to 1000 °C. The resultant mass loss curve was much smoother for the Al-doped material, indicating the beneficial impact of Al3+ addition on the formation process. XRD and spectroscopic (MIR, Raman, magic angle spinning (MAS) NMR) research revealed the formation of an amorphous silsesquioxane xerogel with a slightly modified ladder-like structure, and silicon oxycarbide glasses successfully doped with Al3+ ions, after aging and annealing, respectively. Moreover, NMR studies confirmed the introduction of aluminum into the glass network, based on the presence of Q4(1Al) and [AlO4] species in the 29Si and 27Al MAS NMR spectra, respectively. Additionally, the results from EDS and Raman spectroscopic studies suggested the partial release of free carbon phase from the glass network because of cationic substitution and ordering influence of Al3+ cations on the glass structure." @default.
• W2896608559 created "2018-10-26" @default.
• W2896608559 creator A5018863029 @default.
• W2896608559 creator A5025699410 @default.
• W2896608559 creator A5033223723 @default.
• W2896608559 creator A5057916877 @default.
• W2896608559 creator A5072192392 @default.
• W2896608559 creator A5073432517 @default.
• W2896608559 creator A5080362230 @default.
• W2896608559 date "2019-02-01" @default.
• W2896608559 modified "2023-10-15" @default.
• W2896608559 title "SiAlOC glasses derived from sol-gel synthesized ladder-like silsesquioxanes" @default.
• W2896608559 cites W1198498872 @default.
• W2896608559 cites W1508015035 @default.
• W2896608559 cites W1528479854 @default.
• W2896608559 cites W16159856 @default.
• W2896608559 cites W1895530033 @default.
• W2896608559 cites W1970663420 @default.
• W2896608559 cites W1971703356 @default.
• W2896608559 cites W1974446637 @default.
• W2896608559 cites W1980587374 @default.
• W2896608559 cites W1981549705 @default.
• W2896608559 cites W1984154726 @default.
• W2896608559 cites W1988618986 @default.
• W2896608559 cites W1993087871 @default.
• W2896608559 cites W2000726955 @default.
• W2896608559 cites W2002662701 @default.
• W2896608559 cites W2005336996 @default.
• W2896608559 cites W2005358363 @default.
• W2896608559 cites W2005854686 @default.
• W2896608559 cites W2008098588 @default.
• W2896608559 cites W2024071064 @default.
• W2896608559 cites W2037623096 @default.
• W2896608559 cites W2038157523 @default.
• W2896608559 cites W2038157657 @default.
• W2896608559 cites W2041123002 @default.
• W2896608559 cites W2048664949 @default.
• W2896608559 cites W2049850956 @default.
• W2896608559 cites W2050170127 @default.
• W2896608559 cites W2053266346 @default.
• W2896608559 cites W2064248284 @default.
• W2896608559 cites W2064304763 @default.
• W2896608559 cites W2065906124 @default.
• W2896608559 cites W2069475055 @default.
• W2896608559 cites W2072929299 @default.
• W2896608559 cites W2073253944 @default.
• W2896608559 cites W2078174131 @default.
• W2896608559 cites W2082432733 @default.
• W2896608559 cites W2086133746 @default.
• W2896608559 cites W2089790059 @default.
• W2896608559 cites W2092976652 @default.
• W2896608559 cites W2095284502 @default.
• W2896608559 cites W2101547800 @default.
• W2896608559 cites W2116913214 @default.
• W2896608559 cites W2118703016 @default.
• W2896608559 cites W2123847529 @default.
• W2896608559 cites W2133061058 @default.
• W2896608559 cites W2161530205 @default.
• W2896608559 cites W2169643570 @default.
• W2896608559 cites W2171302889 @default.
• W2896608559 cites W2210858462 @default.
• W2896608559 cites W2235679284 @default.
• W2896608559 cites W2288644194 @default.
• W2896608559 cites W2315731344 @default.
• W2896608559 cites W2316983792 @default.
• W2896608559 cites W2544985100 @default.
• W2896608559 cites W2594848192 @default.
• W2896608559 cites W260809863 @default.
• W2896608559 cites W2617620023 @default.
• W2896608559 cites W2623568130 @default.
• W2896608559 cites W2753491591 @default.
• W2896608559 cites W2762617493 @default.
• W2896608559 cites W2792554551 @default.
• W2896608559 cites W4237830593 @default.
• W2896608559 cites W1966785583 @default.
• W2896608559 cites W2725991258 @default.
• W2896608559 doi "https://doi.org/10.1016/j.ceramint.2018.10.047" @default.
• W2896608559 hasPublicationYear "2019" @default.
• W2896608559 type Work @default.
• W2896608559 sameAs 2896608559 @default.
• W2896608559 citedByCount "22" @default.
• W2896608559 countsByYear W28966085592019 @default.
• W2896608559 countsByYear W28966085592020 @default.
• W2896608559 countsByYear W28966085592021 @default.
• W2896608559 countsByYear W28966085592022 @default.
• W2896608559 countsByYear W28966085592023 @default.
• W2896608559 crossrefType "journal-article" @default.
• W2896608559 hasAuthorship W2896608559A5018863029 @default.
• W2896608559 hasAuthorship W2896608559A5025699410 @default.
• W2896608559 hasAuthorship W2896608559A5033223723 @default.
• W2896608559 hasAuthorship W2896608559A5057916877 @default.
• W2896608559 hasAuthorship W2896608559A5072192392 @default.
• W2896608559 hasAuthorship W2896608559A5073432517 @default.
• W2896608559 hasAuthorship W2896608559A5080362230 @default.
• W2896608559 hasConcept C127413603 @default.
• W2896608559 hasConcept C159985019 @default.
• W2896608559 hasConcept C171250308 @default.
• W2896608559 hasConcept C192562407 @default.

• next