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- W2896643225 abstract "Air- and light-stable electrophilic difluoromethylating reagents, S-(difluoromethyl)- S-phenyl- S-(2,4,6-trialkoxyphenyl) sulfonium salts were successfully developed, and the introduction of intramolecular hydrogen bonds plays a crucial role for the stabilities and reactivities of these reagents. C-selective difluoromethylation of a broad range of β-ketoesters and malonates proceeded smoothly under mild reaction conditions to give good to excellent yields with excellent C/O regioselectivities." @default.
- W2896643225 created "2018-10-26" @default.
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- W2896643225 date "2018-10-12" @default.
- W2896643225 modified "2023-10-18" @default.
- W2896643225 title "Air- and Light-Stable <i>S</i>-(Difluoromethyl)sulfonium Salts: <i>C</i>-Selective Electrophilic Difluoromethylation of β-Ketoesters and Malonates" @default.
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- W2896643225 doi "https://doi.org/10.1021/acs.orglett.8b03067" @default.
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