FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2896663909> ?p ?o ?g. }

• W2896663909 endingPage "16514" @default.
• W2896663909 startingPage "16503" @default.
• W2896663909 abstract "Co3O4/TiO2 nanocomposites with different Co/Ti molar ratios were prepared by hydrolysis of cobalt acetate with urea in the presence of TiO2, and then calcined at 260 °C. Compared to pure TiO2, the Co3O4/TiO2 nanocomposite with the optimum Co/Ti molar ratio of 0.30 demonstrates significantly enhanced catalytic activity as well as excellent catalytic durability for abatement of refractory poisonous benzene (a typical air pollutant) with ultraviolet–visible-infrared (UV–vis-IR) irradiation. It also exhibits effective catalytic activity for benzene abatement even with λ > 830 nm IR irradiation. Its very high catalytic activity derives from light-driven thermocatalytic benzene oxidation on nano Co3O4 in the Co3O4/TiO2 nanocomposite. A novel synergetic effect among light-driven thermocatalysis on Co3O4 and UV photocatalysis on TiO2 in the Co3O4/TiO2 nanocomposite is discovered to remarkably promote catalytic activity and improve catalytic durability by inhibiting the formation of refractory carbonaceous intermediates on TiO2 by photocatalysis: energetic species produced by UV photocatalysis on TiO2 move from TiO2 to Co3O4 through the interface between nano Co3O4 and TiO2, thus accelerating the light-driven thermocatalytic benzene oxidation on nano Co3O4. A novel photoactivation, completely different from photocatalysis on TiO2, is discovered to further considerably accelerate light-driven thermocatalytic activity of Co3O4: Irradiation not only promotes the activity of lattice oxygen of nano Co3O4 but also accelerates the reoxidation of the reduced cobalt oxide (Co3O4–x), resulting in a considerable enhancement in the light-driven thermocatalytic activity of Co3O4. The light-driven themocatalysis together with the novel photocatalysis–thermocatalysis synergetic effect and photoactivation in the Co3O4/TiO2 nanocomposite cause a tremendous enhancement of 489 times in benzene mineralization rate (initial production rate of CO2) as compared to the photocatalytic benzene abatement under UV–vis-IR irradiation with the same light intensity at near room temperature." @default.
• W2896663909 created "2018-10-26" @default.
• W2896663909 creator A5032483419 @default.
• W2896663909 creator A5035615265 @default.
• W2896663909 creator A5052441498 @default.
• W2896663909 creator A5063457276 @default.
• W2896663909 creator A5070340856 @default.
• W2896663909 creator A5083450374 @default.
• W2896663909 creator A5088932013 @default.
• W2896663909 creator A5069750480 @default.
• W2896663909 date "2018-10-21" @default.
• W2896663909 modified "2023-10-14" @default.
• W2896663909 title "Co₃O₄/TiO₂ Nanocomposite Formation Leads to Improvement in Ultraviolet–Visible-Infrared-Driven Thermocatalytic Activity Due to Photoactivation and Photocatalysis–Thermocatalysis Synergetic Effect" @default.
• W2896663909 cites W1420830543 @default.
• W2896663909 cites W1429904039 @default.
• W2896663909 cites W1770543064 @default.
• W2896663909 cites W1965353168 @default.
• W2896663909 cites W1965993928 @default.
• W2896663909 cites W1971710129 @default.
• W2896663909 cites W1972477609 @default.
• W2896663909 cites W1974336007 @default.
• W2896663909 cites W1974700610 @default.
• W2896663909 cites W1976492109 @default.
• W2896663909 cites W1976909790 @default.
• W2896663909 cites W1977753182 @default.
• W2896663909 cites W1978383254 @default.
• W2896663909 cites W1982473217 @default.
• W2896663909 cites W1985453487 @default.
• W2896663909 cites W1985534373 @default.
• W2896663909 cites W1993886961 @default.
• W2896663909 cites W1997105520 @default.
• W2896663909 cites W2002263805 @default.
• W2896663909 cites W2007975760 @default.
• W2896663909 cites W2015301356 @default.
• W2896663909 cites W2019873312 @default.
• W2896663909 cites W2027901279 @default.
• W2896663909 cites W2027952412 @default.
• W2896663909 cites W2029586376 @default.
• W2896663909 cites W2034336389 @default.
• W2896663909 cites W2038340732 @default.
• W2896663909 cites W2040022618 @default.
• W2896663909 cites W2044842642 @default.
• W2896663909 cites W2051578140 @default.
• W2896663909 cites W2055052122 @default.
• W2896663909 cites W2074124696 @default.
• W2896663909 cites W2086350100 @default.
• W2896663909 cites W2086367354 @default.
• W2896663909 cites W2088397156 @default.
• W2896663909 cites W2090315039 @default.
• W2896663909 cites W2091633783 @default.
• W2896663909 cites W2096952190 @default.
• W2896663909 cites W2099498970 @default.
• W2896663909 cites W2112731251 @default.
• W2896663909 cites W2113418833 @default.
• W2896663909 cites W2116234122 @default.
• W2896663909 cites W2119585240 @default.
• W2896663909 cites W2146926579 @default.
• W2896663909 cites W2159454093 @default.
• W2896663909 cites W2275668394 @default.
• W2896663909 cites W2312350480 @default.
• W2896663909 cites W2313406594 @default.
• W2896663909 cites W2313628710 @default.
• W2896663909 cites W2314339524 @default.
• W2896663909 cites W2317669274 @default.
• W2896663909 cites W2317900193 @default.
• W2896663909 cites W2320689837 @default.
• W2896663909 cites W2321071020 @default.
• W2896663909 cites W2321336759 @default.
• W2896663909 cites W2329530087 @default.
• W2896663909 cites W2332145902 @default.
• W2896663909 cites W2333287031 @default.
• W2896663909 cites W2334650844 @default.
• W2896663909 cites W2345190075 @default.
• W2896663909 cites W2387742079 @default.
• W2896663909 cites W2409577250 @default.
• W2896663909 cites W2511134229 @default.
• W2896663909 cites W2563108882 @default.
• W2896663909 cites W2569601998 @default.
• W2896663909 cites W2573899674 @default.
• W2896663909 cites W2593022341 @default.
• W2896663909 cites W2594141286 @default.
• W2896663909 cites W2605174754 @default.
• W2896663909 cites W2735775893 @default.
• W2896663909 cites W2748249917 @default.
• W2896663909 cites W2760264085 @default.
• W2896663909 cites W2765388194 @default.
• W2896663909 cites W2771021344 @default.
• W2896663909 cites W2784528786 @default.
• W2896663909 cites W2792610293 @default.
• W2896663909 cites W2797158657 @default.
• W2896663909 cites W2803120725 @default.
• W2896663909 cites W918905338 @default.
• W2896663909 cites W982791814 @default.
• W2896663909 doi "https://doi.org/10.1021/acssuschemeng.8b03602" @default.
• W2896663909 hasPublicationYear "2018" @default.
• W2896663909 type Work @default.
• W2896663909 sameAs 2896663909 @default.
• W2896663909 citedByCount "48" @default.

• next