FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2896777910> ?p ?o ?g. }

• W2896777910 endingPage "24651" @default.
• W2896777910 startingPage "24634" @default.
• W2896777910 abstract "The present study is a part of an experimental microkinetic approach (EMA) of the selective reduction of NOx to N2 with NH3 in excess O2 on V2O5/WO3/TiO2 catalysts (NH3-SCR process). In the temperature range of interest for NH3-SCR (T ≥≈ 473 K) and for three TiO2-based solids (sulfated and sulfate-free TiO2 supports and a sulfated 0.7% V2O5/9% WO3/TiO2 catalyst), FTIR spectroscopy and volumetric measurements with a mass spectrometer are used to study the impacts of the NH3–H2O coadsorption on the coverages of (a) the molecularly adsorbed NH3 species and (b) the molecularly and dissociated H2O species on Lewis and Brønsted sites. Whatever the solid, it is shown that NH3 dominates the molecular coadsorption on the Lewis sites. However, this does not prevent the dissociative H2O chemisorption on a small amount of Lewis acidic sites, leading to an increase in the amount of OH groups. On the two sulfated solids, these OH groups increase the amount of adsorbed NH4+ species as compared to the NH3 adsorption equilibrium. For the sulfate-free TiO2 solid having weak Brønsted sites, the switch between the NH3 adsorption equilibrium to the NH3–H2O coadsorption equilibrium is associated to the production of a small amount of NH3 due to the displacement of NH3ads-L species by H2O dissociation (competitive adsorption). It is shown that these experimental data are consistent with an original development of a competitive Temkin model (named Temkin-C), taking into account the individual heats of adsorption of NH3 and H2O species at different coverages in the absence of competition. The EMA and Temkin-C model developed in the present study can be applied to all solids having a significant IR transmission offering a method to study the surface acidity during realistic experimental conditions (in the presence of H2O), which is of interest for different catalytic processes such as NH3-SCR and alcohol dehydration." @default.
• W2896777910 created "2018-10-26" @default.
• W2896777910 creator A5001315402 @default.
• W2896777910 creator A5019171239 @default.
• W2896777910 creator A5021477782 @default.
• W2896777910 creator A5035362460 @default.
• W2896777910 creator A5043440547 @default.
• W2896777910 creator A5054959671 @default.
• W2896777910 creator A5062785864 @default.
• W2896777910 creator A5080574403 @default.
• W2896777910 creator A5083102678 @default.
• W2896777910 date "2018-10-10" @default.
• W2896777910 modified "2023-10-18" @default.
• W2896777910 title "Experimental Microkinetic Approach of De-NO_<i>x</i> by NH₃ on V₂O₅/WO₃/TiO₂ Catalysts. 6. NH₃–H₂O Coadsorption on TiO₂-Based Solids and Competitive Temkin Model" @default.
• W2896777910 cites W109716537 @default.
• W2896777910 cites W1528531950 @default.
• W2896777910 cites W1967752079 @default.
• W2896777910 cites W1974472254 @default.
• W2896777910 cites W1976140311 @default.
• W2896777910 cites W1976195165 @default.
• W2896777910 cites W1977281809 @default.
• W2896777910 cites W1980359898 @default.
• W2896777910 cites W1983806547 @default.
• W2896777910 cites W2002717952 @default.
• W2896777910 cites W2007214419 @default.
• W2896777910 cites W2007782101 @default.
• W2896777910 cites W2007913924 @default.
• W2896777910 cites W2007933661 @default.
• W2896777910 cites W2011220864 @default.
• W2896777910 cites W2011999657 @default.
• W2896777910 cites W2017956358 @default.
• W2896777910 cites W2020217767 @default.
• W2896777910 cites W2020583632 @default.
• W2896777910 cites W2020687561 @default.
• W2896777910 cites W2021380186 @default.
• W2896777910 cites W2026965879 @default.
• W2896777910 cites W2028368369 @default.
• W2896777910 cites W2032750975 @default.
• W2896777910 cites W2033752074 @default.
• W2896777910 cites W2041830440 @default.
• W2896777910 cites W2049248516 @default.
• W2896777910 cites W2053293232 @default.
• W2896777910 cites W2059510471 @default.
• W2896777910 cites W2060189956 @default.
• W2896777910 cites W2060675608 @default.
• W2896777910 cites W2062685012 @default.
• W2896777910 cites W2062977213 @default.
• W2896777910 cites W2064743173 @default.
• W2896777910 cites W2072616759 @default.
• W2896777910 cites W2074051828 @default.
• W2896777910 cites W2074788342 @default.
• W2896777910 cites W2078903981 @default.
• W2896777910 cites W2079910927 @default.
• W2896777910 cites W2080708932 @default.
• W2896777910 cites W2087094127 @default.
• W2896777910 cites W2088392024 @default.
• W2896777910 cites W2088999009 @default.
• W2896777910 cites W2089638549 @default.
• W2896777910 cites W2168665169 @default.
• W2896777910 cites W2299238454 @default.
• W2896777910 cites W2313392355 @default.
• W2896777910 cites W2314574065 @default.
• W2896777910 cites W2316181093 @default.
• W2896777910 cites W2326657285 @default.
• W2896777910 cites W2333628727 @default.
• W2896777910 cites W2517148349 @default.
• W2896777910 cites W2594310144 @default.
• W2896777910 cites W2628096580 @default.
• W2896777910 cites W2740114535 @default.
• W2896777910 cites W2745926653 @default.
• W2896777910 cites W2897921576 @default.
• W2896777910 cites W2950536471 @default.
• W2896777910 cites W4229606611 @default.
• W2896777910 doi "https://doi.org/10.1021/acs.jpcc.8b05847" @default.
• W2896777910 hasPublicationYear "2018" @default.
• W2896777910 type Work @default.
• W2896777910 sameAs 2896777910 @default.
• W2896777910 citedByCount "10" @default.
• W2896777910 countsByYear W28967779102018 @default.
• W2896777910 countsByYear W28967779102019 @default.
• W2896777910 countsByYear W28967779102020 @default.
• W2896777910 countsByYear W28967779102021 @default.
• W2896777910 countsByYear W28967779102022 @default.
• W2896777910 countsByYear W28967779102023 @default.
• W2896777910 crossrefType "journal-article" @default.
• W2896777910 hasAuthorship W2896777910A5001315402 @default.
• W2896777910 hasAuthorship W2896777910A5019171239 @default.
• W2896777910 hasAuthorship W2896777910A5021477782 @default.
• W2896777910 hasAuthorship W2896777910A5035362460 @default.
• W2896777910 hasAuthorship W2896777910A5043440547 @default.
• W2896777910 hasAuthorship W2896777910A5054959671 @default.
• W2896777910 hasAuthorship W2896777910A5062785864 @default.
• W2896777910 hasAuthorship W2896777910A5080574403 @default.
• W2896777910 hasAuthorship W2896777910A5083102678 @default.
• W2896777910 hasConcept C102931765 @default.
• W2896777910 hasConcept C105923489 @default.
• W2896777910 hasConcept C113196181 @default.
• W2896777910 hasConcept C121332964 @default.

• next