FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2896783677> ?p ?o ?g. }

• W2896783677 endingPage "4741" @default.
• W2896783677 startingPage "4731" @default.
• W2896783677 abstract "The complexation reaction mechanism of acetylacetone bis‐thiosemicarbazone ligands (H 2 acacR) with Cu II is explored using a variety of physical methods. The complexes form via a complicated multistep mechanism that is initiated by ring opening of the pyrazoline form of the ligand and leads, ultimately in air, to an oxidised ketone form of the ligand. Tetradentate N 2 S 2 coordinated forms of the intermediate [Cu(acacR)] are stable only under anaerobic conditions. Upon exposure to air these complexes are cleanly oxidised to the ketone complex [Cu(acacRO)] as shown by X‐ray crystallography, electrochemistry, UV/Vis and EPR spectroscopy. The behavior of these complexes contrasts with those of closely related bis‐dithiocarbazate Schiff bases which stabilise Cu III ." @default.
• W2896783677 created "2018-10-26" @default.
• W2896783677 creator A5042922201 @default.
• W2896783677 creator A5046623546 @default.
• W2896783677 creator A5057319709 @default.
• W2896783677 date "2018-11-21" @default.
• W2896783677 modified "2023-09-30" @default.
• W2896783677 title "Formation and Reactivity of Copper Acetylacetone Bis(Thiosemicarbazone) Complexes" @default.
• W2896783677 cites W1278207187 @default.
• W2896783677 cites W1890571765 @default.
• W2896783677 cites W1972244400 @default.
• W2896783677 cites W1976307780 @default.
• W2896783677 cites W1980028514 @default.
• W2896783677 cites W1999141192 @default.
• W2896783677 cites W2000301966 @default.
• W2896783677 cites W2001431373 @default.
• W2896783677 cites W2002501551 @default.
• W2896783677 cites W2003345342 @default.
• W2896783677 cites W2012028281 @default.
• W2896783677 cites W2012401203 @default.
• W2896783677 cites W2018665187 @default.
• W2896783677 cites W2021268395 @default.
• W2896783677 cites W2027681891 @default.
• W2896783677 cites W2033879214 @default.
• W2896783677 cites W2041641407 @default.
• W2896783677 cites W2059020082 @default.
• W2896783677 cites W2061148943 @default.
• W2896783677 cites W2063334178 @default.
• W2896783677 cites W2066111168 @default.
• W2896783677 cites W2074394476 @default.
• W2896783677 cites W2078931912 @default.
• W2896783677 cites W2080359657 @default.
• W2896783677 cites W2086353553 @default.
• W2896783677 cites W2131350133 @default.
• W2896783677 cites W2160425502 @default.
• W2896783677 cites W2184171565 @default.
• W2896783677 cites W2235044763 @default.
• W2896783677 cites W2331349227 @default.
• W2896783677 cites W2346148059 @default.
• W2896783677 cites W2782743464 @default.
• W2896783677 doi "https://doi.org/10.1002/ejic.201801002" @default.
• W2896783677 hasPublicationYear "2018" @default.
• W2896783677 type Work @default.
• W2896783677 sameAs 2896783677 @default.
• W2896783677 citedByCount "10" @default.
• W2896783677 countsByYear W28967836772019 @default.
• W2896783677 countsByYear W28967836772020 @default.
• W2896783677 countsByYear W28967836772021 @default.
• W2896783677 countsByYear W28967836772022 @default.
• W2896783677 countsByYear W28967836772023 @default.
• W2896783677 crossrefType "journal-article" @default.
• W2896783677 hasAuthorship W2896783677A5042922201 @default.
• W2896783677 hasAuthorship W2896783677A5046623546 @default.
• W2896783677 hasAuthorship W2896783677A5057319709 @default.
• W2896783677 hasBestOaLocation W28967836771 @default.
• W2896783677 hasConcept C116569031 @default.
• W2896783677 hasConcept C121332964 @default.
• W2896783677 hasConcept C142724271 @default.
• W2896783677 hasConcept C155647269 @default.
• W2896783677 hasConcept C170493617 @default.
• W2896783677 hasConcept C178790620 @default.
• W2896783677 hasConcept C179104552 @default.
• W2896783677 hasConcept C185592680 @default.
• W2896783677 hasConcept C187961010 @default.
• W2896783677 hasConcept C188027245 @default.
• W2896783677 hasConcept C204787440 @default.
• W2896783677 hasConcept C2776910235 @default.
• W2896783677 hasConcept C2777738585 @default.
• W2896783677 hasConcept C2780002320 @default.
• W2896783677 hasConcept C2780744904 @default.
• W2896783677 hasConcept C46141821 @default.
• W2896783677 hasConcept C544778455 @default.
• W2896783677 hasConcept C55493867 @default.
• W2896783677 hasConcept C71924100 @default.
• W2896783677 hasConcept C75473681 @default.
• W2896783677 hasConcept C83591994 @default.
• W2896783677 hasConceptScore W2896783677C116569031 @default.
• W2896783677 hasConceptScore W2896783677C121332964 @default.
• W2896783677 hasConceptScore W2896783677C142724271 @default.
• W2896783677 hasConceptScore W2896783677C155647269 @default.
• W2896783677 hasConceptScore W2896783677C170493617 @default.
• W2896783677 hasConceptScore W2896783677C178790620 @default.
• W2896783677 hasConceptScore W2896783677C179104552 @default.
• W2896783677 hasConceptScore W2896783677C185592680 @default.
• W2896783677 hasConceptScore W2896783677C187961010 @default.
• W2896783677 hasConceptScore W2896783677C188027245 @default.
• W2896783677 hasConceptScore W2896783677C204787440 @default.
• W2896783677 hasConceptScore W2896783677C2776910235 @default.
• W2896783677 hasConceptScore W2896783677C2777738585 @default.
• W2896783677 hasConceptScore W2896783677C2780002320 @default.
• W2896783677 hasConceptScore W2896783677C2780744904 @default.
• W2896783677 hasConceptScore W2896783677C46141821 @default.
• W2896783677 hasConceptScore W2896783677C544778455 @default.
• W2896783677 hasConceptScore W2896783677C55493867 @default.
• W2896783677 hasConceptScore W2896783677C71924100 @default.
• W2896783677 hasConceptScore W2896783677C75473681 @default.
• W2896783677 hasConceptScore W2896783677C83591994 @default.
• W2896783677 hasFunder F4320334704 @default.

• next