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- W2896795063 abstract "Bis(2-hydroxybenzylidene)isophthalohydrazide (H4L) has been used to synthesize the dinuclear [Cu2(1κNO2:2κN′O′2-H2L)(NO3)2(H2O)2] (1) and the tetranuclear [Cu4(μ-1κNO2:2κN′O2-H2L)2(μ-NO3)2(H2O)4]·2C2H5OH (2) complexes. The solvent plays an important role in determining the ligand behaviour in the syntheses of the complexes. An ethanol-acetonitrile mixture of solvents favours partials enolization in the case of 2. Both complexes have been characterized by elemental analysis, infrared radiation (IR), single crystal X-ray crystallography and electrochemical methods. The variable temperature magnetic susceptibility measurements of 2 show strong antiferromagnetic coupling between the central nitrato-bridged Cu (II) ions. The catalytic activity of both 1 and 2 has been screened toward the solvent-free microwave-assisted oxidation of alcohols and the peroxidative oxidation of alkanes under mild conditions. Complex 1 exhibits the highest activity for both oxidation reactions, leading selectively to a maximum product yield of 99% (for the 1-phenylethanol oxidation after 1 h without any additive) and 13% (for the cyclohexane oxidation to cyclohexyl hydroperoxide, cyclohexanol and cyclohexanone after 3 h)." @default.
- W2896795063 created "2018-10-26" @default.
- W2896795063 creator A5026175853 @default.
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- W2896795063 creator A5087821619 @default.
- W2896795063 date "2018-10-19" @default.
- W2896795063 modified "2023-09-29" @default.
- W2896795063 title "Peroxidative Oxidation of Alkanes and Alcohols under Mild Conditions by Di- and Tetranuclear Copper (II) Complexes of Bis (2-Hydroxybenzylidene) Isophthalohydrazide" @default.
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- W2896795063 doi "https://doi.org/10.3390/molecules23102699" @default.
- W2896795063 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6222479" @default.
- W2896795063 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30347723" @default.
- W2896795063 hasPublicationYear "2018" @default.
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