FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2896832983> ?p ?o ?g. }

• W2896832983 endingPage "470" @default.
• W2896832983 startingPage "460" @default.
• W2896832983 abstract "Liquid–liquid phase equilibrium (LLE) data for the {tricyanomethanide-based ionic liquid (1) + tiophene, or benzothiophene (2) + heptane (3)} ternary systems were experimentally determined at T = 308.15 K and at pressure p = 0.1 MPa. In this work three ILs, that is: 1-butyl-1-methylmorpholinium tricyanomethanide, [BMMOR][TCM], 1-butyl-1-methylpyrrolidinium tricyanomethanide, [BMPYR][TCM] and 1-hexyl-1-methylmorpholinium tricyanomethanide, [HMMOR][TCM] have been investigated. The high solubility of sulfur compounds and practically complete immiscibility of heptane with the tested ionic liquids have been observed. The selectivity, S12 and solute distribution ratio, k12 derived from the experimental equilibrium data, were calculated and used to determine the efficiency of these ionic liquids as solvents for the extraction of sulfur compounds from model fuels. The experimental results have been compared to literature data for other tricyanomethanide-based ILs and were discussed in terms of the selectivity and solute distribution ratio of separation of related systems. The NRTL equation was successfully used to correlate the experimental tie-lines. The average root mean square (RMSD) of the phase composition was less than 0.8%. Additionally, the oxidative-extractive desulfurization of model fuels has been studied using tricyanomethanide-based ionic liquid (IL): [BMMOR][TCM] and [BMPYR][TCM] and deep eutectic solvent (DES): ([BMMOR] [Br] + diethylene glycol). Model liquid fuel was prepared by dissolving benzothiophene in octane, 500 ppm of sulfur. Oxidation was achieved by adding hydrogen peroxide and acetic acid to the mixture. Different parameters such as a type of extractant, extraction time, and oxidant to sulfur molar ratio and temperature were optimized. The addition of oxidizing agent improves the efficiency of sulfur extraction and the highest extraction efficiency, equal to 69.1%, was obtained for [BMMOR][TCM] at T = 318.15 K." @default.
• W2896832983 created "2018-10-26" @default.
• W2896832983 creator A5065208188 @default.
• W2896832983 date "2019-04-01" @default.
• W2896832983 modified "2023-10-10" @default.
• W2896832983 title "Liquid–liquid extraction of sulfur compounds from heptane with tricyanomethanide based ionic liquids" @default.
• W2896832983 cites W1177613978 @default.
• W2896832983 cites W1435027157 @default.
• W2896832983 cites W1967351937 @default.
• W2896832983 cites W1969601511 @default.
• W2896832983 cites W1973420634 @default.
• W2896832983 cites W1976569217 @default.
• W2896832983 cites W1983382475 @default.
• W2896832983 cites W1986963892 @default.
• W2896832983 cites W1991393477 @default.
• W2896832983 cites W1993827419 @default.
• W2896832983 cites W1994309906 @default.
• W2896832983 cites W1996965828 @default.
• W2896832983 cites W2000256897 @default.
• W2896832983 cites W2001001450 @default.
• W2896832983 cites W2006808626 @default.
• W2896832983 cites W2009531426 @default.
• W2896832983 cites W2022286350 @default.
• W2896832983 cites W2024560886 @default.
• W2896832983 cites W2028969126 @default.
• W2896832983 cites W2029849449 @default.
• W2896832983 cites W2032011864 @default.
• W2896832983 cites W2032028788 @default.
• W2896832983 cites W2040568265 @default.
• W2896832983 cites W2044095666 @default.
• W2896832983 cites W2050572549 @default.
• W2896832983 cites W2058900912 @default.
• W2896832983 cites W2063147446 @default.
• W2896832983 cites W2064275969 @default.
• W2896832983 cites W2069720541 @default.
• W2896832983 cites W2072013055 @default.
• W2896832983 cites W2072976106 @default.
• W2896832983 cites W2074811734 @default.
• W2896832983 cites W2079769276 @default.
• W2896832983 cites W2084176418 @default.
• W2896832983 cites W2088488605 @default.
• W2896832983 cites W2091994129 @default.
• W2896832983 cites W2100960849 @default.
• W2896832983 cites W2145021857 @default.
• W2896832983 cites W2146983219 @default.
• W2896832983 cites W2153854318 @default.
• W2896832983 cites W2157186817 @default.
• W2896832983 cites W2158204556 @default.
• W2896832983 cites W2163740573 @default.
• W2896832983 cites W2169634129 @default.
• W2896832983 cites W2171250148 @default.
• W2896832983 cites W2211953637 @default.
• W2896832983 cites W2294355217 @default.
• W2896832983 cites W2295056214 @default.
• W2896832983 cites W2300992891 @default.
• W2896832983 cites W2312764592 @default.
• W2896832983 cites W2326628073 @default.
• W2896832983 cites W2329961042 @default.
• W2896832983 cites W2335293608 @default.
• W2896832983 cites W2557854771 @default.
• W2896832983 cites W2742254074 @default.
• W2896832983 cites W2802217306 @default.
• W2896832983 cites W313872787 @default.
• W2896832983 cites W4241094973 @default.
• W2896832983 doi "https://doi.org/10.1016/j.jct.2018.10.009" @default.
• W2896832983 hasPublicationYear "2019" @default.
• W2896832983 type Work @default.
• W2896832983 sameAs 2896832983 @default.
• W2896832983 citedByCount "33" @default.
• W2896832983 countsByYear W28968329832019 @default.
• W2896832983 countsByYear W28968329832020 @default.
• W2896832983 countsByYear W28968329832021 @default.
• W2896832983 countsByYear W28968329832022 @default.
• W2896832983 countsByYear W28968329832023 @default.
• W2896832983 crossrefType "journal-article" @default.
• W2896832983 hasAuthorship W2896832983A5065208188 @default.
• W2896832983 hasConcept C154881586 @default.
• W2896832983 hasConcept C155574463 @default.
• W2896832983 hasConcept C161790260 @default.
• W2896832983 hasConcept C170961132 @default.
• W2896832983 hasConcept C178790620 @default.
• W2896832983 hasConcept C179104552 @default.
• W2896832983 hasConcept C184651966 @default.
• W2896832983 hasConcept C185592680 @default.
• W2896832983 hasConcept C2777854178 @default.
• W2896832983 hasConcept C2779303843 @default.
• W2896832983 hasConcept C2779953032 @default.
• W2896832983 hasConcept C40117563 @default.
• W2896832983 hasConceptScore W2896832983C154881586 @default.
• W2896832983 hasConceptScore W2896832983C155574463 @default.
• W2896832983 hasConceptScore W2896832983C161790260 @default.
• W2896832983 hasConceptScore W2896832983C170961132 @default.
• W2896832983 hasConceptScore W2896832983C178790620 @default.
• W2896832983 hasConceptScore W2896832983C179104552 @default.
• W2896832983 hasConceptScore W2896832983C184651966 @default.
• W2896832983 hasConceptScore W2896832983C185592680 @default.
• W2896832983 hasConceptScore W2896832983C2777854178 @default.
• W2896832983 hasConceptScore W2896832983C2779303843 @default.

• next