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- W2896853863 abstract "In this paper, the thermodynamic properties of the complex species of the Gantrez (Trade Mark product) copolymers of different molecular weights (AN169, S97, and S95) with different divalent (Ca2+, Mg2+, Sn2+, and Zn2+) metal cations in NaCl aqueous solutions at different ionic strengths and temperatures were studied by a potentiometric technique. Investigations were carried out in wide ranges of metal to ligand molar concentration ratios up to basic pH values. For the simple metal-Gantrez systems, fairly similar speciation models were obtained, independent of the experimental conditions; the main differences are due to the formation of a ternary MLOH species (M = metal ion, L = Gantrez ligand) or to the final pH value of the titrations, determined by the formation in some cases (i.e., for Sn2+ investigations) of a sparingly soluble species. The stability trend of the species was: Sn2+ ≫ Zn2+ > Ca2+ ≈ Mg2+. For Gantrez S95, the interactions with Zn2+ and Sn2+ were also investigated in a solution containin..." @default.
- W2896853863 created "2018-10-26" @default.
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- W2896853863 date "2018-10-19" @default.
- W2896853863 modified "2023-09-28" @default.
- W2896853863 title "Use of Gantrez Copolymers as Potential Chelating Agent for the Selective Sequestration of Metal Ions. Studies of the Interactions in Aqueous Solution at Different Ionic Strengths and Temperatures" @default.
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- W2896853863 doi "https://doi.org/10.1021/acs.jced.8b00655" @default.
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