Matches in SemOpenAlex for { <https://semopenalex.org/work/W2896904046> ?p ?o ?g. }
- W2896904046 endingPage "13646" @default.
- W2896904046 startingPage "13636" @default.
- W2896904046 abstract "We report herein a precise control of the electrochemical bistability induced by surface area changes during the cathodic deposition of copper. Small additions of 1,10-phenanthroline (Phen) in the reaction media present an inhibiting effect on the global rate mainly due to the adsorption of protonated Phen. The increase of its concentration favors a shrinkage of the bifurcation (saddle-node) diagram and shifts it to less negative potentials. The dynamic instability is verified by impedance measurements, and a negative impedance is clearly found. We calculated the apparent molar mass of the adsorbents using in situ gravimetric monitoring in the electrochemical experiments, and the results indicate that mass changes occur mainly due to the reduction of copper from bivalent ions dissolved in the reaction media. Importantly, the adsorption of protonated Phen molecules does not show a considerable contribution in mass variations but prevents the formation of a copper course grained morphology over the surface. Imaging analysis indicates finer nodulations at the lower branch compared to the upper branch in the bistability domain. On the basis of these observations, a kinetic mechanism is proposed and a good agreement is obtained between the apparent molar mass extracted from experiments and the theoretical values. Altogether, our results contribute to a detailed physical chemical description of the nonlinear behavior, bringing new insights about this reaction and pointing out the possibility to design switchable surface electrodes by taking advantage of the bistable behavior." @default.
- W2896904046 created "2018-10-26" @default.
- W2896904046 creator A5004973088 @default.
- W2896904046 creator A5023418140 @default.
- W2896904046 creator A5024711661 @default.
- W2896904046 creator A5038194431 @default.
- W2896904046 creator A5075048105 @default.
- W2896904046 date "2018-10-19" @default.
- W2896904046 modified "2023-10-16" @default.
- W2896904046 title "Tuning Electrochemical Bistability by Surface Area Blocking in the Cathodic Deposition of Copper" @default.
- W2896904046 cites W1548574614 @default.
- W2896904046 cites W1562725551 @default.
- W2896904046 cites W1964189212 @default.
- W2896904046 cites W1967142909 @default.
- W2896904046 cites W1967628170 @default.
- W2896904046 cites W1972755878 @default.
- W2896904046 cites W1973437246 @default.
- W2896904046 cites W1976848277 @default.
- W2896904046 cites W1984964350 @default.
- W2896904046 cites W1989276588 @default.
- W2896904046 cites W1990968533 @default.
- W2896904046 cites W1994094797 @default.
- W2896904046 cites W1994108919 @default.
- W2896904046 cites W1994726051 @default.
- W2896904046 cites W1997585234 @default.
- W2896904046 cites W1998285743 @default.
- W2896904046 cites W2002001836 @default.
- W2896904046 cites W2002737214 @default.
- W2896904046 cites W2004404788 @default.
- W2896904046 cites W2005687021 @default.
- W2896904046 cites W2012453956 @default.
- W2896904046 cites W2013606324 @default.
- W2896904046 cites W2013695874 @default.
- W2896904046 cites W2014486507 @default.
- W2896904046 cites W2018382364 @default.
- W2896904046 cites W2020213073 @default.
- W2896904046 cites W2021206395 @default.
- W2896904046 cites W2025573566 @default.
- W2896904046 cites W2027020630 @default.
- W2896904046 cites W2029213898 @default.
- W2896904046 cites W2029649578 @default.
- W2896904046 cites W2029868881 @default.
- W2896904046 cites W2030173912 @default.
- W2896904046 cites W2031810649 @default.
- W2896904046 cites W2032145407 @default.
- W2896904046 cites W2038850910 @default.
- W2896904046 cites W2039974708 @default.
- W2896904046 cites W2040323430 @default.
- W2896904046 cites W2040755140 @default.
- W2896904046 cites W2041635330 @default.
- W2896904046 cites W2047840356 @default.
- W2896904046 cites W2049181513 @default.
- W2896904046 cites W2055500540 @default.
- W2896904046 cites W2055576019 @default.
- W2896904046 cites W2060263619 @default.
- W2896904046 cites W2068444828 @default.
- W2896904046 cites W2068754912 @default.
- W2896904046 cites W2073470977 @default.
- W2896904046 cites W2078978190 @default.
- W2896904046 cites W2091321531 @default.
- W2896904046 cites W2093820376 @default.
- W2896904046 cites W2094791856 @default.
- W2896904046 cites W2113887370 @default.
- W2896904046 cites W2118372461 @default.
- W2896904046 cites W2143937451 @default.
- W2896904046 cites W2149695636 @default.
- W2896904046 cites W2157746304 @default.
- W2896904046 cites W2162487090 @default.
- W2896904046 cites W2356580269 @default.
- W2896904046 cites W2402562963 @default.
- W2896904046 cites W2461115542 @default.
- W2896904046 cites W2604531286 @default.
- W2896904046 cites W2605221223 @default.
- W2896904046 cites W2686396682 @default.
- W2896904046 cites W2737546963 @default.
- W2896904046 cites W2745903616 @default.
- W2896904046 cites W2746094390 @default.
- W2896904046 cites W2756662835 @default.
- W2896904046 cites W2770092889 @default.
- W2896904046 cites W2797441563 @default.
- W2896904046 cites W3098703851 @default.
- W2896904046 cites W3105315250 @default.
- W2896904046 cites W4239670818 @default.
- W2896904046 cites W4247025065 @default.
- W2896904046 doi "https://doi.org/10.1021/acsomega.8b02353" @default.
- W2896904046 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6644789" @default.
- W2896904046 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31458069" @default.
- W2896904046 hasPublicationYear "2018" @default.
- W2896904046 type Work @default.
- W2896904046 sameAs 2896904046 @default.
- W2896904046 citedByCount "6" @default.
- W2896904046 countsByYear W28969040462019 @default.
- W2896904046 countsByYear W28969040462020 @default.
- W2896904046 countsByYear W28969040462023 @default.
- W2896904046 crossrefType "journal-article" @default.
- W2896904046 hasAuthorship W2896904046A5004973088 @default.
- W2896904046 hasAuthorship W2896904046A5023418140 @default.
- W2896904046 hasAuthorship W2896904046A5024711661 @default.