FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2896958782> ?p ?o ?g. }

• W2896958782 endingPage "17726" @default.
• W2896958782 startingPage "17719" @default.
• W2896958782 abstract "A luminescent TbIII complex with a hexafluoroacetylacetone (hfa) ligand shows a characteristic back energy transfer (BEnT), which leads to high temperature sensitivity and potential application as a thermosensitive paint. Ligand-assisted BEnT was observed when a phosphine oxide ligand was introduced into Tb(hfa)3 complex, which was shown to affect the activation energy (ΔEa ) and frequency factor (A) in the BEnT process between TbIII ion and hfa ligands. According to temperature-dependent emission-lifetime measurements of mononuclear Tb(hfa)3 complexes with monodentate phosphine oxides and polynuclear Tb(hfa)3 complexes with bidentate phosphine oxides, the ΔEa and A values of polynuclear TbIII complexes were smaller than those of mononuclear TbIII complexes. Phosphorescence spectra and lifetimes of each Gd(hfa)3 complex revealed that excited states of hfa ligands in TbIII complexes differed from those of the polynuclear TbIII complexes and mononuclear TbIII complexes. The differences in the ΔEa and A values between polynuclear and mononuclear TbIII complexes were caused by the formation of different excited states, such as delocalization of the excited state in the polynuclear TbIII complexes and localization of excited states in the mononuclear TbIII complexes. In particular, small ΔEa and A values of polynuclear TbIII complexes provided high, effective activation of the BEnT at low temperature, which resulted in high-sensitive temperature-dependent phosphor materials over a wide temperature range." @default.
• W2896958782 created "2018-10-26" @default.
• W2896958782 creator A5029676343 @default.
• W2896958782 creator A5031507015 @default.
• W2896958782 creator A5049078425 @default.
• W2896958782 creator A5049691035 @default.
• W2896958782 creator A5079584054 @default.
• W2896958782 date "2018-11-22" @default.
• W2896958782 modified "2023-10-16" @default.
• W2896958782 title "Ligand-Assisted Back Energy Transfer in Luminescent Tb^III Complexes for Thermosensing Properties" @default.
• W2896958782 cites W1963961835 @default.
• W2896958782 cites W1970406991 @default.
• W2896958782 cites W1989199054 @default.
• W2896958782 cites W2003758809 @default.
• W2896958782 cites W2009477800 @default.
• W2896958782 cites W2016091392 @default.
• W2896958782 cites W2023271753 @default.
• W2896958782 cites W2025898924 @default.
• W2896958782 cites W2029825894 @default.
• W2896958782 cites W2043974385 @default.
• W2896958782 cites W2066551370 @default.
• W2896958782 cites W2073854819 @default.
• W2896958782 cites W2078935438 @default.
• W2896958782 cites W2087762156 @default.
• W2896958782 cites W2088954215 @default.
• W2896958782 cites W2100042879 @default.
• W2896958782 cites W2115822581 @default.
• W2896958782 cites W2132114812 @default.
• W2896958782 cites W2132582838 @default.
• W2896958782 cites W2143981217 @default.
• W2896958782 cites W2153734311 @default.
• W2896958782 cites W2159085311 @default.
• W2896958782 cites W2162138395 @default.
• W2896958782 cites W2171743368 @default.
• W2896958782 cites W2210283409 @default.
• W2896958782 cites W2213945912 @default.
• W2896958782 cites W2316528740 @default.
• W2896958782 cites W2327526185 @default.
• W2896958782 cites W2473731816 @default.
• W2896958782 cites W2507636780 @default.
• W2896958782 cites W2516832007 @default.
• W2896958782 cites W2550222796 @default.
• W2896958782 cites W2603315154 @default.
• W2896958782 cites W2615857900 @default.
• W2896958782 cites W2753497316 @default.
• W2896958782 cites W2770158411 @default.
• W2896958782 cites W2772788650 @default.
• W2896958782 cites W4230453967 @default.
• W2896958782 cites W4246541092 @default.
• W2896958782 cites W4249399279 @default.
• W2896958782 cites W958428485 @default.
• W2896958782 doi "https://doi.org/10.1002/chem.201804392" @default.
• W2896958782 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30325067" @default.
• W2896958782 hasPublicationYear "2018" @default.
• W2896958782 type Work @default.
• W2896958782 sameAs 2896958782 @default.
• W2896958782 citedByCount "29" @default.
• W2896958782 countsByYear W28969587822019 @default.
• W2896958782 countsByYear W28969587822020 @default.
• W2896958782 countsByYear W28969587822021 @default.
• W2896958782 countsByYear W28969587822022 @default.
• W2896958782 countsByYear W28969587822023 @default.
• W2896958782 crossrefType "journal-article" @default.
• W2896958782 hasAuthorship W2896958782A5029676343 @default.
• W2896958782 hasAuthorship W2896958782A5031507015 @default.
• W2896958782 hasAuthorship W2896958782A5049078425 @default.
• W2896958782 hasAuthorship W2896958782A5049691035 @default.
• W2896958782 hasAuthorship W2896958782A5079584054 @default.
• W2896958782 hasBestOaLocation W28969587822 @default.
• W2896958782 hasConcept C115624301 @default.
• W2896958782 hasConcept C116569031 @default.
• W2896958782 hasConcept C121332964 @default.
• W2896958782 hasConcept C138211643 @default.
• W2896958782 hasConcept C147789679 @default.
• W2896958782 hasConcept C148869448 @default.
• W2896958782 hasConcept C161790260 @default.
• W2896958782 hasConcept C170493617 @default.
• W2896958782 hasConcept C178516000 @default.
• W2896958782 hasConcept C178790620 @default.
• W2896958782 hasConcept C181500209 @default.
• W2896958782 hasConcept C181817918 @default.
• W2896958782 hasConcept C184779094 @default.
• W2896958782 hasConcept C185592680 @default.
• W2896958782 hasConcept C192562407 @default.
• W2896958782 hasConcept C2777716191 @default.
• W2896958782 hasConcept C2781082197 @default.
• W2896958782 hasConcept C49040817 @default.
• W2896958782 hasConcept C55493867 @default.
• W2896958782 hasConcept C62520636 @default.
• W2896958782 hasConcept C75473681 @default.
• W2896958782 hasConcept C8010536 @default.
• W2896958782 hasConcept C91881484 @default.
• W2896958782 hasConcept C95121573 @default.
• W2896958782 hasConceptScore W2896958782C115624301 @default.
• W2896958782 hasConceptScore W2896958782C116569031 @default.
• W2896958782 hasConceptScore W2896958782C121332964 @default.
• W2896958782 hasConceptScore W2896958782C138211643 @default.
• W2896958782 hasConceptScore W2896958782C147789679 @default.

• next