FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2896965154> ?p ?o ?g. }

• W2896965154 endingPage "4030" @default.
• W2896965154 startingPage "4024" @default.
• W2896965154 abstract "Zn(DCTC) (DCTC = 3,6-dichlorodithiacatecholate) reacts with Mo(NAd)(CHCMe2Ph)Cl2(PPh2Me) (Ad = 1-adamantyl) to give Mo(NAd)(CHCMe2Ph)(DCTC)(PPh2Me). The reactions between Zn(DCTC) and Mo(NAd)(CH-t-Bu)(OTf)2(dme) or Mo(NAr)(CHCMe2Ph)(OTf)2(dme) (Ar = 2,6-i-Pr2C6H3; OTf = triflate; dme = 1,2-dimethoxyethane) produce [Mo(NAd)(CH-t-Bu)(DCTC)]2 and [Mo(NAr)(CHCMe2Ph)(DCTC)]2, respectively. Complexes that contain a 3,3′,5,5′-tetrasubstituted dithiabiphenolate were prepared in a reaction between Mo(NAr)(CHCMe2Ph)(Me2pyr)2 (Me2pyr = 2,5-dimethylpyrrolide) and the 3,3′,5,5′-tetrasubstituted dithiabiphenols, (3,3′,5,5′-tetrachlorodithiabiphenol (H2Cl4S2), 3,3′,5,5′-tetrabromodithiabiphenol (H2Br4S2), and 3,3′,5,5′-tetra-t-Bu-dithiabiphenol (H2Bu4S2)). The isolated complexes include Mo(NAr)(CHCMe2Ph)(Cl4S2)(pyridine), Mo(NAr)(CHCMe2Ph)(Br4S2)(pyridine), Mo(NAr)(CHCMe2Ph)(Bu4S2)(PMe3), and [Mo(NAr)(CHCMe2Ph)(Cl4S2)]2. Only the dithiabiphenolate derivatives (in the presence of B(C6F5)3) show activity for the metathesis of 1-decene, and although that reaction is limited by a sensitivity of the alkylidene complexes to ethylene, as suggested by the reaction between ethylene and Mo(NAr)(CHCMe2Ph)(Bu4S2) to give the ethylene complex, Mo(NAr)(C2H4)(Bu4S2). Mo(NAr)(C2H4)(Bu4S2) was unstable with respect to loss of ethylene and formation of an ethylene-free dimer. Mo(NAd)(CHCMe2Ph)(DCTC)(PPh2Me), [Mo(NAr)(CHCMe2Ph)(DCTC)]2, and [Mo(NAr)(CHCMe2Ph)(Cl4S2)]2 were characterized crystallographically." @default.
• W2896965154 created "2018-10-26" @default.
• W2896965154 creator A5003443234 @default.
• W2896965154 creator A5039462753 @default.
• W2896965154 creator A5050979141 @default.
• W2896965154 creator A5079660000 @default.
• W2896965154 date "2018-10-18" @default.
• W2896965154 modified "2023-09-27" @default.
• W2896965154 title "Syntheses of Molybdenum(VI) Imido Alkylidene Complexes That Contain a Bidentate Dithiolate Ligand" @default.
• W2896965154 cites W1965682723 @default.
• W2896965154 cites W1967637833 @default.
• W2896965154 cites W1967824835 @default.
• W2896965154 cites W1974206831 @default.
• W2896965154 cites W1977422850 @default.
• W2896965154 cites W1978680029 @default.
• W2896965154 cites W1981427204 @default.
• W2896965154 cites W2000869936 @default.
• W2896965154 cites W2002718914 @default.
• W2896965154 cites W2005546983 @default.
• W2896965154 cites W2006839983 @default.
• W2896965154 cites W2010189672 @default.
• W2896965154 cites W2013228321 @default.
• W2896965154 cites W2024785697 @default.
• W2896965154 cites W2026517688 @default.
• W2896965154 cites W2027497231 @default.
• W2896965154 cites W2028690227 @default.
• W2896965154 cites W2030340979 @default.
• W2896965154 cites W2036354248 @default.
• W2896965154 cites W2038662926 @default.
• W2896965154 cites W2040529547 @default.
• W2896965154 cites W2044645250 @default.
• W2896965154 cites W2048233559 @default.
• W2896965154 cites W2065262927 @default.
• W2896965154 cites W2066037930 @default.
• W2896965154 cites W2069676303 @default.
• W2896965154 cites W2087144630 @default.
• W2896965154 cites W2094225092 @default.
• W2896965154 cites W2105249240 @default.
• W2896965154 cites W2112391736 @default.
• W2896965154 cites W2260428529 @default.
• W2896965154 cites W2330325608 @default.
• W2896965154 cites W2333247784 @default.
• W2896965154 cites W2528115455 @default.
• W2896965154 cites W2549849171 @default.
• W2896965154 cites W2580674650 @default.
• W2896965154 cites W2602996545 @default.
• W2896965154 cites W2624856888 @default.
• W2896965154 cites W2761782979 @default.
• W2896965154 cites W2766147810 @default.
• W2896965154 cites W2766825152 @default.
• W2896965154 cites W2793694857 @default.
• W2896965154 doi "https://doi.org/10.1021/acs.organomet.8b00614" @default.
• W2896965154 hasPublicationYear "2018" @default.
• W2896965154 type Work @default.
• W2896965154 sameAs 2896965154 @default.
• W2896965154 citedByCount "4" @default.
• W2896965154 countsByYear W28969651542019 @default.
• W2896965154 countsByYear W28969651542020 @default.
• W2896965154 countsByYear W28969651542022 @default.
• W2896965154 crossrefType "journal-article" @default.
• W2896965154 hasAuthorship W2896965154A5003443234 @default.
• W2896965154 hasAuthorship W2896965154A5039462753 @default.
• W2896965154 hasAuthorship W2896965154A5050979141 @default.
• W2896965154 hasAuthorship W2896965154A5079660000 @default.
• W2896965154 hasConcept C115624301 @default.
• W2896965154 hasConcept C116569031 @default.
• W2896965154 hasConcept C147789679 @default.
• W2896965154 hasConcept C153914509 @default.
• W2896965154 hasConcept C155647269 @default.
• W2896965154 hasConcept C161790260 @default.
• W2896965154 hasConcept C170493617 @default.
• W2896965154 hasConcept C17525397 @default.
• W2896965154 hasConcept C178516000 @default.
• W2896965154 hasConcept C178790620 @default.
• W2896965154 hasConcept C179104552 @default.
• W2896965154 hasConcept C181199279 @default.
• W2896965154 hasConcept C185592680 @default.
• W2896965154 hasConcept C21774173 @default.
• W2896965154 hasConcept C2778597550 @default.
• W2896965154 hasConcept C2778734912 @default.
• W2896965154 hasConcept C2779485729 @default.
• W2896965154 hasConcept C2779546866 @default.
• W2896965154 hasConcept C44228677 @default.
• W2896965154 hasConcept C521977710 @default.
• W2896965154 hasConcept C549387045 @default.
• W2896965154 hasConcept C55493867 @default.
• W2896965154 hasConcept C68801617 @default.
• W2896965154 hasConcept C71240020 @default.
• W2896965154 hasConcept C75520062 @default.
• W2896965154 hasConcept C8010536 @default.
• W2896965154 hasConceptScore W2896965154C115624301 @default.
• W2896965154 hasConceptScore W2896965154C116569031 @default.
• W2896965154 hasConceptScore W2896965154C147789679 @default.
• W2896965154 hasConceptScore W2896965154C153914509 @default.
• W2896965154 hasConceptScore W2896965154C155647269 @default.
• W2896965154 hasConceptScore W2896965154C161790260 @default.
• W2896965154 hasConceptScore W2896965154C170493617 @default.
• W2896965154 hasConceptScore W2896965154C17525397 @default.

• next