FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2897015412> ?p ?o ?g. }

• W2897015412 endingPage "424" @default.
• W2897015412 startingPage "412" @default.
• W2897015412 abstract "This article describes the influence of different solvents on the versatility of coordination-networks, formed from alkali metal coordination complex and transition metal bis(dithiolato) complex [M(btdt)2]1− (M = Cu(III) and Au(III); btdt = 2,1,3-benzenethiadiazole-5,6-dithiolate) in compounds 1–7: {[Na(CH3OH)4][Cu(btdt)2]}n (1), {[Na(THF)4][Cu(btdt)2]}n (2), {[Na(CH3COCH3)2][Cu(btdt)2]}n (3), {[Na(DMF)2][Cu(btdt)2]}n (4), {[Na(CH3CN)2][Cu(btdt)2]}n (5) {[Na(THF)2][Na(THF)(OH2)] [Au2(btdt)4]}n (6) and {[Na(CH3COCH3)2][Au(btdt)2]}n (7). The coordination polymers 1–5, based on copper(III)-bis(dithiolene) complex [CuIII(btdt)2]1−, are synthesized by the recrystallization of a dark-brown coloured precipitated precursor (P1) having a black appearance from the different solvents. The precursor P1 was obtained by the reaction of one mole equivalent of CuCl2·2H2O with two mole equivalents of H2btdt in MeOH, treated with an excess amount of NaOH in an open air atmosphere. For the preparation of compounds 6 and 7, AuCl3·2H2O was treated with H2btdt in MeOH containing NaOH to obtain precipitated precursor P2, which was recrystallized from THF and acetone to produce single crystals of 6 and 7 respectively. In the crystal structures of coordination polymers 1–7, where sodium coordination complex is a cationic component, the dimensionality of the networks of the resulting coordination polymers has greatly been influenced by the nature of hybridization of central carbon atom of the sodium-coordinated solvent, which happens to be the recrystallizing solvent. In order to investigate the influence of the counter cation on the structural diversity and dimensionality, we have compared the supramolecular chemistry of these sodium metal based coordination polymers 1–7 with that of our previously reported potassium-based coordination polymers {[K(CH3COCH3)3][Cu(btdt)2]}n and {[K(CH3CN)2][Cu(btdt)2]}n. All these compounds have been characterized unambiguously by single crystal X-ray crystallography and routine spectroscopy (IR, UV-visible and NMR). Interestingly, copper compounds 1 and 3–5 exhibit two quasi-reversible reduction responses at −0.13 V and −1.10 V vs Ag/AgCl respectively in DMF solutions." @default.
• W2897015412 created "2018-10-26" @default.
• W2897015412 creator A5004375913 @default.
• W2897015412 creator A5068700119 @default.
• W2897015412 creator A5070564138 @default.
• W2897015412 date "2019-02-01" @default.
• W2897015412 modified "2023-10-18" @default.
• W2897015412 title "Coordination polymers from dithiolato complexes and alkali metal cations: How a crystallizing and coordinating solvent influences the dimensionality" @default.
• W2897015412 cites W1530128299 @default.
• W2897015412 cites W1567007829 @default.
• W2897015412 cites W1849043974 @default.
• W2897015412 cites W1910151573 @default.
• W2897015412 cites W1943758292 @default.
• W2897015412 cites W1964699956 @default.
• W2897015412 cites W1965526767 @default.
• W2897015412 cites W1970034545 @default.
• W2897015412 cites W1970686145 @default.
• W2897015412 cites W1972100581 @default.
• W2897015412 cites W1972646318 @default.
• W2897015412 cites W1977748201 @default.
• W2897015412 cites W1977961375 @default.
• W2897015412 cites W1978659336 @default.
• W2897015412 cites W1983559425 @default.
• W2897015412 cites W1984586122 @default.
• W2897015412 cites W1985509245 @default.
• W2897015412 cites W1990492621 @default.
• W2897015412 cites W1990878315 @default.
• W2897015412 cites W1997531531 @default.
• W2897015412 cites W1999711169 @default.
• W2897015412 cites W1999908724 @default.
• W2897015412 cites W2001290572 @default.
• W2897015412 cites W2005454218 @default.
• W2897015412 cites W2006377435 @default.
• W2897015412 cites W2007068681 @default.
• W2897015412 cites W2011879584 @default.
• W2897015412 cites W2012319734 @default.
• W2897015412 cites W2013313682 @default.
• W2897015412 cites W2013373157 @default.
• W2897015412 cites W2014965018 @default.
• W2897015412 cites W2018064719 @default.
• W2897015412 cites W2020113710 @default.
• W2897015412 cites W2020912262 @default.
• W2897015412 cites W2022218117 @default.
• W2897015412 cites W2029287154 @default.
• W2897015412 cites W2029700477 @default.
• W2897015412 cites W2030637195 @default.
• W2897015412 cites W2030841140 @default.
• W2897015412 cites W2035689641 @default.
• W2897015412 cites W2035952367 @default.
• W2897015412 cites W2039614230 @default.
• W2897015412 cites W2040963553 @default.
• W2897015412 cites W2042981124 @default.
• W2897015412 cites W2047212438 @default.
• W2897015412 cites W2050065836 @default.
• W2897015412 cites W2050931815 @default.
• W2897015412 cites W2056221033 @default.
• W2897015412 cites W2057786191 @default.
• W2897015412 cites W2060442820 @default.
• W2897015412 cites W2061713587 @default.
• W2897015412 cites W2062462303 @default.
• W2897015412 cites W2066686362 @default.
• W2897015412 cites W2067815548 @default.
• W2897015412 cites W2076050093 @default.
• W2897015412 cites W2076939671 @default.
• W2897015412 cites W2077329807 @default.
• W2897015412 cites W2081111117 @default.
• W2897015412 cites W2082561386 @default.
• W2897015412 cites W2084190453 @default.
• W2897015412 cites W2086115670 @default.
• W2897015412 cites W2090530864 @default.
• W2897015412 cites W2094508515 @default.
• W2897015412 cites W2094682831 @default.
• W2897015412 cites W2097239055 @default.
• W2897015412 cites W2099497386 @default.
• W2897015412 cites W2105907151 @default.
• W2897015412 cites W2107011450 @default.
• W2897015412 cites W2123165315 @default.
• W2897015412 cites W2123900245 @default.
• W2897015412 cites W2131350133 @default.
• W2897015412 cites W2133445047 @default.
• W2897015412 cites W2144806170 @default.
• W2897015412 cites W2147854232 @default.
• W2897015412 cites W2158744361 @default.
• W2897015412 cites W2161236549 @default.
• W2897015412 cites W2165167119 @default.
• W2897015412 cites W2171499252 @default.
• W2897015412 cites W2314530261 @default.
• W2897015412 cites W2891670902 @default.
• W2897015412 doi "https://doi.org/10.1016/j.ica.2018.10.041" @default.
• W2897015412 hasPublicationYear "2019" @default.
• W2897015412 type Work @default.
• W2897015412 sameAs 2897015412 @default.
• W2897015412 citedByCount "8" @default.
• W2897015412 countsByYear W28970154122019 @default.
• W2897015412 countsByYear W28970154122020 @default.
• W2897015412 countsByYear W28970154122022 @default.
• W2897015412 crossrefType "journal-article" @default.
• W2897015412 hasAuthorship W2897015412A5004375913 @default.

• next