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- W2897022418 endingPage "6895" @default.
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- W2897022418 abstract "An unprecedented efficient palladium(0)-catalyzed reaction of vinyl oxiranes with N-tosylhydrazones, affording “skipped” allylic alcohols in total regioselectivity and stereoselectivity, with excellent functional-group compatibility, is reported. In this Tsuji–Trost-like allylation, we propose the use of N-tosylhydrazones as a synthetic equivalent of α-styryl anions. More than 20 new products are described, including naturally occurring derivatives. A catalytic system involving an iodide (I–) source is necessary to sustain the catalytic cycle." @default.
- W2897022418 created "2018-10-26" @default.
- W2897022418 creator A5018131642 @default.
- W2897022418 creator A5076995888 @default.
- W2897022418 date "2018-10-18" @default.
- W2897022418 modified "2023-10-16" @default.
- W2897022418 title "Synthesis of Highly Functionalized Allylic Alcohols from Vinyl Oxiranes and <i>N</i>-Tosylhydrazones via a Tsuji–Trost-Like “Palladium–Iodide” Catalyzed Coupling" @default.
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- W2897022418 doi "https://doi.org/10.1021/acs.orglett.8b03026" @default.
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- W2897022418 hasPublicationYear "2018" @default.
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