Matches in SemOpenAlex for { <https://semopenalex.org/work/W2897023897> ?p ?o ?g. }
- W2897023897 endingPage "24214" @default.
- W2897023897 startingPage "24209" @default.
- W2897023897 abstract "Efficiently utilizing alkanes as the precursors to realize various chemical reaction processes is challenging due to the inertness of alkane C–H bonds. We report here the selective C–H activation and C–C coupling reaction of linear alkanes on Au-covered Ag(110) surfaces. Based on density functional theory calculations, thin gold films with a thickness of several atomic layers deposited on Ag(110) resemble the bulk Au(110) surface for alkane C–H bond activation. By using scanning tunneling microscopy (STM) we have observed that, instead of linear C–C coupling on unalloyed Au(110), alkane molecules desorb from Ag(110) surfaces at elevated temperatures. The featured missing-row (1 × 2) reconstruction of Au(110) surfaces has been obtained by deposition of ∼20 ML (<3 nm) gold atoms on Ag(110). On such reconstructed surface, linear alkane polymerization through selective C–H activation and C–C coupling has been achieved at mild temperatures. Our work demonstrates the possibility to utilize thin gold films replacing bulk Au(110) substrates for selective alkyl C–H bond activation." @default.
- W2897023897 created "2018-10-26" @default.
- W2897023897 creator A5007846775 @default.
- W2897023897 creator A5007922418 @default.
- W2897023897 creator A5038250994 @default.
- W2897023897 creator A5045128616 @default.
- W2897023897 creator A5050440394 @default.
- W2897023897 creator A5065905349 @default.
- W2897023897 creator A5076336029 @default.
- W2897023897 date "2018-10-09" @default.
- W2897023897 modified "2023-10-18" @default.
- W2897023897 title "Linear Alkane Polymerization on Au-Covered Ag(110) Surfaces" @default.
- W2897023897 cites W1797597183 @default.
- W2897023897 cites W1964132516 @default.
- W2897023897 cites W1970127494 @default.
- W2897023897 cites W1976521205 @default.
- W2897023897 cites W1979544533 @default.
- W2897023897 cites W1981237763 @default.
- W2897023897 cites W1981368803 @default.
- W2897023897 cites W1987657450 @default.
- W2897023897 cites W1988409555 @default.
- W2897023897 cites W1990797187 @default.
- W2897023897 cites W2000181693 @default.
- W2897023897 cites W2005661768 @default.
- W2897023897 cites W2007395042 @default.
- W2897023897 cites W2028253542 @default.
- W2897023897 cites W2029316586 @default.
- W2897023897 cites W2031430816 @default.
- W2897023897 cites W2044028691 @default.
- W2897023897 cites W2044591029 @default.
- W2897023897 cites W2054404247 @default.
- W2897023897 cites W2061102145 @default.
- W2897023897 cites W2061658015 @default.
- W2897023897 cites W2065798113 @default.
- W2897023897 cites W2072763674 @default.
- W2897023897 cites W2074557853 @default.
- W2897023897 cites W2074767435 @default.
- W2897023897 cites W2079105963 @default.
- W2897023897 cites W2083222334 @default.
- W2897023897 cites W2084644533 @default.
- W2897023897 cites W2085660053 @default.
- W2897023897 cites W2093012528 @default.
- W2897023897 cites W2122427541 @default.
- W2897023897 cites W2123914589 @default.
- W2897023897 cites W2137064863 @default.
- W2897023897 cites W2140372631 @default.
- W2897023897 cites W2154645192 @default.
- W2897023897 cites W2167804158 @default.
- W2897023897 cites W2168174641 @default.
- W2897023897 cites W2180555938 @default.
- W2897023897 cites W2221905205 @default.
- W2897023897 cites W2311228914 @default.
- W2897023897 cites W2567654442 @default.
- W2897023897 cites W2733049073 @default.
- W2897023897 cites W2789268550 @default.
- W2897023897 cites W2798057260 @default.
- W2897023897 cites W4211044815 @default.
- W2897023897 cites W4211164327 @default.
- W2897023897 doi "https://doi.org/10.1021/acs.jpcc.8b09533" @default.
- W2897023897 hasPublicationYear "2018" @default.
- W2897023897 type Work @default.
- W2897023897 sameAs 2897023897 @default.
- W2897023897 citedByCount "7" @default.
- W2897023897 countsByYear W28970238972019 @default.
- W2897023897 countsByYear W28970238972021 @default.
- W2897023897 countsByYear W28970238972022 @default.
- W2897023897 countsByYear W28970238972023 @default.
- W2897023897 crossrefType "journal-article" @default.
- W2897023897 hasAuthorship W2897023897A5007846775 @default.
- W2897023897 hasAuthorship W2897023897A5007922418 @default.
- W2897023897 hasAuthorship W2897023897A5038250994 @default.
- W2897023897 hasAuthorship W2897023897A5045128616 @default.
- W2897023897 hasAuthorship W2897023897A5050440394 @default.
- W2897023897 hasAuthorship W2897023897A5065905349 @default.
- W2897023897 hasAuthorship W2897023897A5076336029 @default.
- W2897023897 hasConcept C147597530 @default.
- W2897023897 hasConcept C147789679 @default.
- W2897023897 hasConcept C150394285 @default.
- W2897023897 hasConcept C152365726 @default.
- W2897023897 hasConcept C161790260 @default.
- W2897023897 hasConcept C162711632 @default.
- W2897023897 hasConcept C171250308 @default.
- W2897023897 hasConcept C178790620 @default.
- W2897023897 hasConcept C185592680 @default.
- W2897023897 hasConcept C19067145 @default.
- W2897023897 hasConcept C192562407 @default.
- W2897023897 hasConcept C2780263894 @default.
- W2897023897 hasConcept C2781327020 @default.
- W2897023897 hasConcept C32909587 @default.
- W2897023897 hasConcept C44228677 @default.
- W2897023897 hasConcept C521977710 @default.
- W2897023897 hasConcept C6518042 @default.
- W2897023897 hasConceptScore W2897023897C147597530 @default.
- W2897023897 hasConceptScore W2897023897C147789679 @default.
- W2897023897 hasConceptScore W2897023897C150394285 @default.
- W2897023897 hasConceptScore W2897023897C152365726 @default.
- W2897023897 hasConceptScore W2897023897C161790260 @default.
- W2897023897 hasConceptScore W2897023897C162711632 @default.