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• W2897024305 endingPage "6402" @default.
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• W2897024305 abstract "A stereoselective protection-free asymmetric total synthesis of (+)-chamuvarinin (1), a potent anticancer and antitrypanosomal agent, has been accomplished. The adjacently linked [bis(tetrahydrofuran)]tetrahydropyran (THF–THF–THP) core of this natural product with seven stereogenic centers was constructed in a completely substrate-controlled fashion. The inter-ring stereochemistry (threo,threo,threo) of the oxatricyclic core was established in a stereoselective fashion by a chelation-controlled Keck allylation, whereas the intraring cis or trans relative stereochemistry was controlled by a stereoselective internal alkylation." @default.
• W2897024305 created "2018-10-26" @default.
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• W2897024305 date "2018-10-08" @default.
• W2897024305 modified "2023-10-15" @default.
• W2897024305 title "Stereoselective Protection-Free Asymmetric Total Synthesis of (+)-Chamuvarinin, a Potent Anticancer and Antitrypanosomal Agent: Substrate-Controlled Construction of the Adjacently Linked Oxatricyclic Core by Internal Alkylation" @default.
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• W2897024305 doi "https://doi.org/10.1021/acs.orglett.8b02706" @default.
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• W2897024305 hasPublicationYear "2018" @default.
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