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- W2897058908 abstract "Abstract The thermal behaviour of an H‐bonded molecular network A based on [Fe II (CN) 6 ] 4− anions and organic bisamidium cations 1 2+ was investigated. Heating was found to induce the partial oxidation of [Fe II (CN) 6 ] 4− into [Fe III (CN) 6 ] 3− , together with a thermochromic effect and also a loss of crystallinity was evidenced from mid and far FT‐IR spectroscopic data, XRPD and DSC/TGA analysis. Rehydration also partially reversed the redox reaction and its colour, and after that, a mixture of A with an amorphous phases was observed. FT‐IR spectroscopy revealed that the oxidation of Fe(II) was accompanied by a deprotonation of the cation." @default.
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- W2897058908 date "2018-10-11" @default.
- W2897058908 modified "2023-09-26" @default.
- W2897058908 title "Partially Reversible Thermal-Induced Oxidation During a Dehydration Process in an H-bonded Supramolecular System" @default.
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- W2897058908 doi "https://doi.org/10.1002/cphc.201800845" @default.
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