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- W2897058995 abstract "This chapter discusses certain aspects of the practical utilization of polymers with special attention to processing stage, which plays a decisive role in deciding if a particular polymeric material can be produced as a marketable commodity. It is customary to quote a glass-transition temperature (Tg) for a polymer because it separates two very different regimes of mechanical behavior. Below Tg, the mass of entangled molecules is rigid. Above Tg, viscoelastic effects come into play and it is therefore the lower temperature limit for processing thermoplastics. The structural effect of raising the temperature of a glassy polymer is to provide an input of thermal energy and to increase the vibrations of constituent atoms and molecules. Molecular mobility increases significantly as Tg is approached: rotation about C–C bonds in the chain molecules begins, the free volume of the structure increases, and intermolecular forces weaken. It becomes easier for applied forces to deform the structure and elastic moduli to fall. Finally, the chapter discusses composites, extending from the well-known glass-reinforced polymers to those based upon ceramic and metallic matrices." @default.
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- W2897058995 date "1995-01-01" @default.
- W2897058995 modified "2023-09-27" @default.
- W2897058995 title "Plastics and composites" @default.
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- W2897058995 doi "https://doi.org/10.1016/b978-0-7506-1093-3.50015-8" @default.
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