Matches in SemOpenAlex for { <https://semopenalex.org/work/W2897066807> ?p ?o ?g. }
- W2897066807 endingPage "13430" @default.
- W2897066807 startingPage "13423" @default.
- W2897066807 abstract "An electronic spectral and photophysical characterization of three gold(I) complexes containing heterocyclic chromophores differing in the number and arrangement of pyridine rings (pyridine, bipyridine, and terpyridine, with the acronyms pD, bD, and tD respectively) was performed. Quantum yields of fluorescence, internal conversion and triplet state formation, together with the rate constants for singlet to triplet intersystem crossing, S1 ∼ ∼ ∼ S0 internal conversion and fluorescence were measured in order to equate the impact of fast triplet state formation on the amount of triplets formed. The results showed a correlation between the increase on the measured decay values of S1 (leading to the main formation of T1) and the increase in the charge transfer (CT) character of the lowest energy transition, as evaluated from the orthogonality of the frontier orbitals. The measured triplet state quantum yields range from ∼50–60% to 70%, whereas the intersystem crossing rate constants differ by almost 2 orders of magnitude, from 9.4 × 109 s–1 for tD to 8.1 × 1011 s–1 for bD. This constitutes an evidence for the existence of a correlation between the intersystem crossing and the internal conversion mechanisms." @default.
- W2897066807 created "2018-10-26" @default.
- W2897066807 creator A5008647291 @default.
- W2897066807 creator A5020090923 @default.
- W2897066807 creator A5034375293 @default.
- W2897066807 creator A5035500368 @default.
- W2897066807 creator A5048501359 @default.
- W2897066807 creator A5054292531 @default.
- W2897066807 creator A5082238534 @default.
- W2897066807 creator A5086927973 @default.
- W2897066807 date "2018-10-10" @default.
- W2897066807 modified "2023-10-15" @default.
- W2897066807 title "Deactivation Routes in Gold(I) Polypyridyl Complexes: Internal Conversion Vs Fast Intersystem Crossing" @default.
- W2897066807 cites W157996412 @default.
- W2897066807 cites W1607456377 @default.
- W2897066807 cites W1963818903 @default.
- W2897066807 cites W1965399283 @default.
- W2897066807 cites W1972924829 @default.
- W2897066807 cites W1974257600 @default.
- W2897066807 cites W1979769141 @default.
- W2897066807 cites W1980893232 @default.
- W2897066807 cites W1982436093 @default.
- W2897066807 cites W1996224669 @default.
- W2897066807 cites W2014884208 @default.
- W2897066807 cites W2020529164 @default.
- W2897066807 cites W2023782776 @default.
- W2897066807 cites W2035526704 @default.
- W2897066807 cites W2038237929 @default.
- W2897066807 cites W2040402456 @default.
- W2897066807 cites W2060099081 @default.
- W2897066807 cites W2061148175 @default.
- W2897066807 cites W2069583799 @default.
- W2897066807 cites W2072891621 @default.
- W2897066807 cites W2072966824 @default.
- W2897066807 cites W2077532881 @default.
- W2897066807 cites W2079968973 @default.
- W2897066807 cites W2079986366 @default.
- W2897066807 cites W2098292174 @default.
- W2897066807 cites W2104016239 @default.
- W2897066807 cites W2124531971 @default.
- W2897066807 cites W2128738505 @default.
- W2897066807 cites W2128909971 @default.
- W2897066807 cites W2129248052 @default.
- W2897066807 cites W2141956399 @default.
- W2897066807 cites W2152916826 @default.
- W2897066807 cites W2153236453 @default.
- W2897066807 cites W2161684171 @default.
- W2897066807 cites W2166120285 @default.
- W2897066807 cites W2166186644 @default.
- W2897066807 cites W2300080238 @default.
- W2897066807 cites W2315234697 @default.
- W2897066807 cites W2325604855 @default.
- W2897066807 cites W2326353536 @default.
- W2897066807 cites W2340358416 @default.
- W2897066807 cites W2487770617 @default.
- W2897066807 cites W2617998079 @default.
- W2897066807 cites W2738911156 @default.
- W2897066807 cites W2739113773 @default.
- W2897066807 cites W2756027481 @default.
- W2897066807 cites W2765610403 @default.
- W2897066807 cites W2953055540 @default.
- W2897066807 cites W4294990658 @default.
- W2897066807 cites W2333696310 @default.
- W2897066807 doi "https://doi.org/10.1021/acs.inorgchem.8b01993" @default.
- W2897066807 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30351079" @default.
- W2897066807 hasPublicationYear "2018" @default.
- W2897066807 type Work @default.
- W2897066807 sameAs 2897066807 @default.
- W2897066807 citedByCount "16" @default.
- W2897066807 countsByYear W28970668072019 @default.
- W2897066807 countsByYear W28970668072020 @default.
- W2897066807 countsByYear W28970668072021 @default.
- W2897066807 countsByYear W28970668072022 @default.
- W2897066807 countsByYear W28970668072023 @default.
- W2897066807 crossrefType "journal-article" @default.
- W2897066807 hasAuthorship W2897066807A5008647291 @default.
- W2897066807 hasAuthorship W2897066807A5020090923 @default.
- W2897066807 hasAuthorship W2897066807A5034375293 @default.
- W2897066807 hasAuthorship W2897066807A5035500368 @default.
- W2897066807 hasAuthorship W2897066807A5048501359 @default.
- W2897066807 hasAuthorship W2897066807A5054292531 @default.
- W2897066807 hasAuthorship W2897066807A5082238534 @default.
- W2897066807 hasAuthorship W2897066807A5086927973 @default.
- W2897066807 hasBestOaLocation W28970668072 @default.
- W2897066807 hasConcept C116039458 @default.
- W2897066807 hasConcept C121332964 @default.
- W2897066807 hasConcept C1276947 @default.
- W2897066807 hasConcept C147120987 @default.
- W2897066807 hasConcept C155647269 @default.
- W2897066807 hasConcept C178790620 @default.
- W2897066807 hasConcept C181500209 @default.
- W2897066807 hasConcept C184779094 @default.
- W2897066807 hasConcept C185592680 @default.
- W2897066807 hasConcept C189394030 @default.
- W2897066807 hasConcept C192468462 @default.
- W2897066807 hasConcept C2779485729 @default.
- W2897066807 hasConcept C32909587 @default.
- W2897066807 hasConcept C33062035 @default.