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- W2897077653 abstract "The robustness of the simulation of bioethanol concentration from sugarcane faces two major challenges: the presence of several minor components and the nonlinear behavior of vapor-liquid equilibrium (VLE) calculations. This work assesses the effect of simplifications to overcome these difficulties. From a set of seventeen substances, methanol, n-propanol, isobutanol, 2-methyl-1-butanol and 3-methyl-1-butanol were selected through the examination of the influence of each minor component on vapor-liquid equilibrium calculations of ethanol-water-third component systems. The selection procedure was based on Txy diagrams built using the modified Raoult's law. The influence of the ratio between the vapor phase fugacity coefficients and of the Poynting correction factor were verified. The accuracy of four correlations for vapor pressure was evaluated, and two functional-group activity coefficient models were scrutinized: the recent Functional-Segment Activity Coefficient (F-SAC) and the UNIFAC-Do model." @default.
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- W2897077653 date "2018-06-01" @default.
- W2897077653 modified "2023-10-16" @default.
- W2897077653 title "VAPOR-LIQUID EQUILIBRIUM CALCULATION FOR SIMULATION OF BIOETHANOL CONCENTRATION FROM SUGARCANE" @default.
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- W2897077653 doi "https://doi.org/10.1590/0104-6632.20180352s20160278" @default.
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