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- W2897083475 abstract "Novel catalytic systems for the Rh-catalyzed hydroformylation of dicyclopentadiene have been developed using tris-H8-binaphthyl monophosphite as ligands containing different ester substituents at the 2'-binaphthyl position (OCOMe, OCOPh, OCOAdamantyl and OCOPhCl). The catalysts exhibited high activity (S/C = 4000, TON = 3286) with good to excellent selectivity towards dialdehydes. Remarkably, the Rh(I) complex bearing the ligands with chlorophenyl ester substituents led to 99.9% conversion and 98.7% selectivity for dialdehydes under relatively mild conditions (6 MPa, 120 °C)." @default.
- W2897083475 created "2018-10-26" @default.
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- W2897083475 date "2018-10-01" @default.
- W2897083475 modified "2023-10-16" @default.
- W2897083475 title "Highly efficient Rh(I)/tris-H8-binaphthyl monophosphite catalysts for hydroformylation of dicyclopentadiene to dialdehydes" @default.
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- W2897083475 doi "https://doi.org/10.1016/s1872-2067(18)63098-0" @default.
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