FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2897087928> ?p ?o ?g. }

• W2897087928 endingPage "13480" @default.
• W2897087928 startingPage "13473" @default.
• W2897087928 abstract "An effective and operationally simple method for the preparation of methyl 2-(di/tri/tetraazol-1-yl)-2H-azirine-2-carboxylates from accessible methyl 2-halo-2H-azirine-2-carboxylates and NH-azoles has been developed. The azoles having enhanced NH acidity, react with 2-halo-2H-azirines in the presence of Et3N in a deprotonated form, while the azoles having highly nucleophilic sp2 nitrogen react in neutral form. According to the DFT calculations, the substitution of the halogen by the azole proceeds via an SN2′-SN2′ cascade, with the initial conjugate substitution of the halogen being the rate-determining step. The formation of 2,3-dipyrazolylaziridines in the reaction of pyrazole provides experimental evidence for the cascade mechanism of the reaction." @default.
• W2897087928 created "2018-10-26" @default.
• W2897087928 creator A5001011772 @default.
• W2897087928 creator A5006629535 @default.
• W2897087928 creator A5036614652 @default.
• W2897087928 creator A5055718145 @default.
• W2897087928 creator A5087558339 @default.
• W2897087928 creator A5090027546 @default.
• W2897087928 date "2018-10-10" @default.
• W2897087928 modified "2023-09-23" @default.
• W2897087928 title "Synthesis of 2-(Di/tri/tetraazolyl)-2<i>H</i>-azirine-2-carboxylates by Halogen Substitution: Evidence for an S_N2′-S_N2′ Cascade Mechanism" @default.
• W2897087928 cites W12343461 @default.
• W2897087928 cites W1622859521 @default.
• W2897087928 cites W1935399211 @default.
• W2897087928 cites W1973175302 @default.
• W2897087928 cites W1979732083 @default.
• W2897087928 cites W1986749585 @default.
• W2897087928 cites W2003389840 @default.
• W2897087928 cites W2033511623 @default.
• W2897087928 cites W2037809940 @default.
• W2897087928 cites W2042364504 @default.
• W2897087928 cites W2046702761 @default.
• W2897087928 cites W2059174306 @default.
• W2897087928 cites W2138994050 @default.
• W2897087928 cites W2169846433 @default.
• W2897087928 cites W2196237611 @default.
• W2897087928 cites W2196795586 @default.
• W2897087928 cites W2317398587 @default.
• W2897087928 cites W2325441686 @default.
• W2897087928 cites W2514182380 @default.
• W2897087928 cites W2522735534 @default.
• W2897087928 cites W2534007282 @default.
• W2897087928 cites W2604324345 @default.
• W2897087928 cites W2624828656 @default.
• W2897087928 cites W2736382726 @default.
• W2897087928 cites W2742633690 @default.
• W2897087928 cites W2772066600 @default.
• W2897087928 cites W2795539622 @default.
• W2897087928 cites W2806129209 @default.
• W2897087928 cites W2949336503 @default.
• W2897087928 cites W2951394659 @default.
• W2897087928 cites W2953035374 @default.
• W2897087928 doi "https://doi.org/10.1021/acs.joc.8b02295" @default.
• W2897087928 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30335384" @default.
• W2897087928 hasPublicationYear "2018" @default.
• W2897087928 type Work @default.
• W2897087928 sameAs 2897087928 @default.
• W2897087928 citedByCount "7" @default.
• W2897087928 countsByYear W28970879282019 @default.
• W2897087928 countsByYear W28970879282020 @default.
• W2897087928 countsByYear W28970879282021 @default.
• W2897087928 countsByYear W28970879282022 @default.
• W2897087928 crossrefType "journal-article" @default.
• W2897087928 hasAuthorship W2897087928A5001011772 @default.
• W2897087928 hasAuthorship W2897087928A5006629535 @default.
• W2897087928 hasAuthorship W2897087928A5036614652 @default.
• W2897087928 hasAuthorship W2897087928A5055718145 @default.
• W2897087928 hasAuthorship W2897087928A5087558339 @default.
• W2897087928 hasAuthorship W2897087928A5090027546 @default.
• W2897087928 hasConcept C111185830 @default.
• W2897087928 hasConcept C118629725 @default.
• W2897087928 hasConcept C135731615 @default.
• W2897087928 hasConcept C145148216 @default.
• W2897087928 hasConcept C155647269 @default.
• W2897087928 hasConcept C16005928 @default.
• W2897087928 hasConcept C178790620 @default.
• W2897087928 hasConcept C185592680 @default.
• W2897087928 hasConcept C199360897 @default.
• W2897087928 hasConcept C2775982830 @default.
• W2897087928 hasConcept C2778220771 @default.
• W2897087928 hasConcept C2779548794 @default.
• W2897087928 hasConcept C2780263894 @default.
• W2897087928 hasConcept C2780315139 @default.
• W2897087928 hasConcept C2780378348 @default.
• W2897087928 hasConcept C34146451 @default.
• W2897087928 hasConcept C41008148 @default.
• W2897087928 hasConcept C43617362 @default.
• W2897087928 hasConcept C46062151 @default.
• W2897087928 hasConcept C71240020 @default.
• W2897087928 hasConcept C71924100 @default.
• W2897087928 hasConcept C96765332 @default.
• W2897087928 hasConceptScore W2897087928C111185830 @default.
• W2897087928 hasConceptScore W2897087928C118629725 @default.
• W2897087928 hasConceptScore W2897087928C135731615 @default.
• W2897087928 hasConceptScore W2897087928C145148216 @default.
• W2897087928 hasConceptScore W2897087928C155647269 @default.
• W2897087928 hasConceptScore W2897087928C16005928 @default.
• W2897087928 hasConceptScore W2897087928C178790620 @default.
• W2897087928 hasConceptScore W2897087928C185592680 @default.
• W2897087928 hasConceptScore W2897087928C199360897 @default.
• W2897087928 hasConceptScore W2897087928C2775982830 @default.
• W2897087928 hasConceptScore W2897087928C2778220771 @default.
• W2897087928 hasConceptScore W2897087928C2779548794 @default.
• W2897087928 hasConceptScore W2897087928C2780263894 @default.
• W2897087928 hasConceptScore W2897087928C2780315139 @default.
• W2897087928 hasConceptScore W2897087928C2780378348 @default.
• W2897087928 hasConceptScore W2897087928C34146451 @default.
• W2897087928 hasConceptScore W2897087928C41008148 @default.

• next