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- W2897089687 abstract "Strong self-association of hydrophobic solutes takes place in water. However, solute self-association has often been neglected in understanding the aqueous solubility of drugs as well as their solubilization by excipients, cosolvents and hydrotropes. Based on a rigorous statistical thermodynamic foundation, here we show how to estimate the contribution from solute self-association to solubility and solubilization, based on experimental data such as solubility and the osmotic second virial coefficients. Such data show that solute self-association can indeed be negligible in most common cases of hydrotropic solubilization, Setschenow coefficients and the hydrophobic hydration." @default.
- W2897089687 created "2018-10-26" @default.
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- W2897089687 date "2019-01-01" @default.
- W2897089687 modified "2023-09-24" @default.
- W2897089687 title "Effect of solute aggregation on solubilization" @default.
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- W2897089687 doi "https://doi.org/10.1016/j.molliq.2018.10.102" @default.
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