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• W2897119921 abstract "Abstract F430 is a unique enzymatic cofactor in the production and oxidation of methane by strictly anaerobic bacteria. The key enzyme methyl coenzyme M reductase (MCR) contains a hydroporphinoid nickel complex with a characteristic absorption maximum at around 430 nm in its active site. Herein, the three‐step semisynthesis of a hybrid Ni II ‐containing corrinoid that partly resembles F430 in its structural and spectroscopic features from vitamin B 12 is presented. A key step of the route is the simultaneous demetalation and ring closure reaction of a 5,6‐secocobalamin to metal‐free 5,6‐dihydroxy‐5,6‐dihydrohydrogenobalamin with cobaltocene and KCN under reductive conditions. Studies on the coordination chemistry of the novel compound support an earlier hypothesis why nature carefully selected a corphin over a corrin ligand in F430 for challenging nickel‐catalyzed biochemical reactions." @default.
• W2897119921 created "2018-10-26" @default.
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• W2897119921 date "2018-11-15" @default.
• W2897119921 modified "2023-10-13" @default.
• W2897119921 title "A Nickel(II)-Containing Vitamin B₁₂Derivative with a Cofactor-F430-type π-System" @default.
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• W2897119921 doi "https://doi.org/10.1002/anie.201810983" @default.
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