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- W2897212291 abstract "We have performed a structural investigation of the high pressure intrusion/extrusion of a series of electrolyte aqueous solutions (NaCl, NaBr, and CaCl2) with different concentrations (2 and 3 M) in a pure-silica chabazite. In situ synchrotron X-ray powder diffraction experiments were performed in the pressure range of 0.12–2.6 GPa and upon pressure release, to unravel the interactions among intruded species and host material. The energetic performances of the systems were determined by porosimetric studies. Results show that the chemical nature of saline solution influences the intrusion–extrusion pressure, whereas the structural evolutions undergone by the systems upon pressure-induced intrusion are essentially independent of the nature of the penetrating media. Moreover, the initial electrolyte concentration influences only the value of the intrusion pressure, but neither the amount nor the interaction mode of the intruded species. Both water and salt molecules enter the pores and the penetration of c..." @default.
- W2897212291 created "2018-10-26" @default.
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- W2897212291 date "2018-10-16" @default.
- W2897212291 modified "2023-10-03" @default.
- W2897212291 title "Intrusion–Extrusion of Electrolyte Aqueous Solutions in Pure Silica Chabazite by in Situ High Pressure Synchrotron X-ray Powder Diffraction" @default.
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- W2897212291 doi "https://doi.org/10.1021/acs.jpcc.8b07338" @default.
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