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- W2897329546 abstract "Two new dinuclear lanthanide(III) compounds based a multidentate Schiff base ligand with the general formula [Ln2(dbm)2L2(CH3OH)2](Ln = Gd (1) and Dy (2), dbm = H2L = N′-(4-(diethylamino)salicylaldehyde)pyridyl-2-carbohydrazide), have been synthesized, structurelly and magnetically characterized. Compounds 1 and 2 are μ2-O bridged dinuclear complexes and each center Ln(III) ion is eight-coordinated with one bidentate dbm−, one CH3OH and two μ2-O bridging Schiff base ligands. Magnetic studies reveal that 1 displays cryogenic magnetic refrigeration property (−ΔSm = 21.1 J kg−1 K−1 for ΔH = 7 T at 2.0 K); while 2 exhibits slow magnetic relaxation behavior under zero dc filed." @default.
- W2897329546 created "2018-10-26" @default.
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- W2897329546 date "2019-02-01" @default.
- W2897329546 modified "2023-10-10" @default.
- W2897329546 title "Two dinuclear lanthanide(III) compounds based on a multidentate ligand: Structures, magnetic refrigeration and slow magnetic relaxation" @default.
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- W2897329546 doi "https://doi.org/10.1016/j.ica.2018.10.045" @default.
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