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- W2897380508 abstract "Two strategies for the design of new pillar[5]arene-based mechanically self-interlocked molecules (MSMs) are reported here. The first strategy is based on the construction of an intermediate pseudo[1]rotaxane followed by the desired bis-[1]rotaxane. The other one is based on the construction of the desired bis-[1]rotaxane directly via a condensation reaction through host-guest interactions between a mono-functionalized pillar[5]arene and the axle. The newly synthesized bis-[1]rotaxane BR was characterized by 1H NMR, 13C NMR, 2D NMRs (1H-13C HSQC, 1H-1H COSY and NOESY) and LC-ESI-MS, which indicated compound BR displayed an self-interlocked structure in CDCl3. Surprisingly, the results of SEM, TEM and DLS showed that the compound BR could assemble into spherical nanoparticles in MeOH." @default.
- W2897380508 created "2018-10-26" @default.
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- W2897380508 date "2019-02-01" @default.
- W2897380508 modified "2023-09-29" @default.
- W2897380508 title "Design and synthesis of self-included pillar[5]arene-based bis-[1]rotaxanes" @default.
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- W2897380508 doi "https://doi.org/10.1016/j.cclet.2018.10.014" @default.
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