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• W2897400140 abstract "The orthogonal sulfur-fluoride exchange reaction (SuFEx) and copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) are employed to synthesize sequence-regulated synthetic polymers. The high efficiency and broad tolerance of SuFEx and CuAAC to diverse chemical functionalities enable the one-pot synthesis of polydispersed sequence-controlled polymers by step-growth copolymerization in high yield and sequence complexity. Furthermore, iterative SuFEx and CuAAC coupling reactions on a solid support, without the need of protecting groups, afford monodispersed sequence-defined oligomers. The use of this orthogonal pair of click reactions provides new opportunities to facilely access sequence-regulated synthetic polymers with a high degree of structural diversity." @default.
• W2897400140 created "2018-10-26" @default.
• W2897400140 creator A5024314944 @default.
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• W2897400140 date "2018-12-03" @default.
• W2897400140 modified "2023-10-16" @default.
• W2897400140 title "Facile Synthesis of Sequence‐Regulated Synthetic Polymers Using Orthogonal SuFEx and CuAAC Click Reactions" @default.
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• W2897400140 doi "https://doi.org/10.1002/anie.201811051" @default.
• W2897400140 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30326185" @default.
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