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• W2897466333 endingPage "6779" @default.
• W2897466333 startingPage "6774" @default.
• W2897466333 abstract "Using methanol as a sustainable C1 source, cobalt-catalyzed α-methoxymethylation and α-aminomethylation of ketones have been developed. With cheap CoCl2·6H2O as catalyst and TBHP as oxidant, the methoxymethylated products were obtained within a short reaction time in up to 91% yield. Based on the observed reversibility of methoxy adduct to enone, the α-aminomethylation of ketones was then achieved by a one-pot methylenation/aza-Michael addition sequence. In addition, an easy way to convert α-methoxymethyl ketones to α-aminomethyl ketones has been discovered." @default.
• W2897466333 created "2018-10-26" @default.
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• W2897466333 date "2018-10-15" @default.
• W2897466333 modified "2023-10-14" @default.
• W2897466333 title "Cobalt-Catalyzed α-Methoxymethylation and Aminomethylation of Ketones with Methanol as a C1 Source" @default.
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• W2897466333 doi "https://doi.org/10.1021/acs.orglett.8b02892" @default.
• W2897466333 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30350664" @default.
• W2897466333 hasPublicationYear "2018" @default.
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