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- W2897472695 abstract "Abstract We synthesized a solid I−/I3−-based redox-couple electrolyte using a mixture of succinonitrile, LiI and I2. An increase of LiI to succinonitrile mole ratio (x) up to 2.5% led to a fast rise in the electrical conductivity (σ25°C) of the electrolytes. Further increase in x slowly increased the σ25°C-value. The composition with x = 5% achieved the highest σ25°C-value (~1.6 × 10−3 S cm−1) and was referred to as the optimum conducting composition (OCC) of the electrolytes. Also, an increase of x led to a decrease of the melting temperature of the electrolytes as suggested by the logσ − T−1 study and ascertained by the differential scanning calorimetry study. The logσ − T−1 study showed a linear trend before and after the melting temperature, and the activation energy increased with increasing x-value. The electrical and thermal properties were explained using the vibrational spectroscopy study. The ionic transference number measurement showed that the electrolytes with x = 4 and 5% are predominantly ionic in nature." @default.
- W2897472695 created "2018-10-26" @default.
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- W2897472695 date "2018-11-01" @default.
- W2897472695 modified "2023-09-24" @default.
- W2897472695 title "Electrical, structural, and thermal properties of succinonitrile-LiI-I2 redox-mediator" @default.
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- W2897472695 doi "https://doi.org/10.1016/j.ssi.2018.10.008" @default.
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