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- W2897500257 endingPage "114" @default.
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- W2897500257 abstract "Bis(guanidine) copper complexes are known for their ability to activate dioxygen. Unfortunately, until now, no bis(guanidine) copper-dioxygen adduct has been able to transfer oxygen to substrates. Using an aromatic backbone, fluorescence properties can be added to the copper(I) complex which renders them useful for later reaction monitoring. The novel bis(guanidine) ligand DMEG2tol stabilizes copper(I) and copper(II) complexes (characterized by single crystal X-ray diffraction, IR spectroscopy, and mass spectrometry) and, after oxygen activation, bis(µ-oxido) dicopper(III) complexes which have been characterized by low-temperature UV/Vis and Raman spectroscopy. These bis(guanidine) stabilized bis(µ-oxido) complexes are able to mediate tyrosinase-like hydroxylation activity as first examples of bis(guanidine) stabilized complexes. The experimental study is accompanied by density functional theory calculations which highlight the special role of the different guanidine donors." @default.
- W2897500257 created "2018-10-26" @default.
- W2897500257 creator A5005730460 @default.
- W2897500257 creator A5009620443 @default.
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- W2897500257 creator A5073157046 @default.
- W2897500257 creator A5087828490 @default.
- W2897500257 creator A5090650515 @default.
- W2897500257 date "2018-10-20" @default.
- W2897500257 modified "2023-09-26" @default.
- W2897500257 title "Fluorescent Bis(guanidine) Copper Complexes as Precursors for Hydroxylation Catalysis" @default.
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- W2897500257 doi "https://doi.org/10.3390/inorganics6040114" @default.