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- W2897519335 abstract "Silylium ions undergo a single-electron reduction with phosphanes, leading to transient silyl radicals and the corresponding stable phosphoniumyl radical cations. As supported by DFT calculations, phosphanes with electron-rich 2,6-disubstituted aryl groups are sufficiently strong reductants to facilitate this single-electron transfer (SET). Frustration as found in kinetically stabilized triarylsilylium ion/phosphane Lewis pairs is not essential, and silylphosphonium ions, which are generated by conventional Lewis adduct formation of solvent-stabilized trialkylsilylium ions and phosphanes, engage in the same radical mechanism. The trityl cation, a Lewis acid with a higher electron affinity, even oxidizes trialkylphosphanes, such as tBu3 P, which does not react with either B(C6 F5 )3 or silylium ions." @default.
- W2897519335 created "2018-10-26" @default.
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- W2897519335 date "2018-11-12" @default.
- W2897519335 modified "2023-10-14" @default.
- W2897519335 title "Single‐Electron Transfer Reactions in Frustrated and Conventional Silylium Ion/Phosphane Lewis Pairs" @default.
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- W2897519335 doi "https://doi.org/10.1002/anie.201808922" @default.
- W2897519335 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30178534" @default.
- W2897519335 hasPublicationYear "2018" @default.
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