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- W2897539966 abstract "Abstract Periclase type Ni/Mg/Al mixed-metal oxide prepared from sol-gel derived SiO2@Ni-Mg-Al Layered Double Hydroxides (LDH) nanocomposite at SiO2:LDH ratios 0:1 and 1:1 was used as a catalyst for catalytic partial oxidation (CPO) of CH4 in presence of N2O as well as oxygen. The catalysts were characterized by XRD, BET surface area, H2-TPR and XPS analysis. The presence of SiO2 dispersant influenced the catalytic property. The nascent oxygen formed by the decomposition of N2O does not re-oxidize Ni0 like molecular oxygen which act as the active species and leads to partial oxidation of CH4. SiO2@Ni-Mg-Al (1:1) catalyst showed about 99.99% H2 and 99.8% CO yield between the temperature range of 200-500 °C." @default.
- W2897539966 created "2018-10-26" @default.
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- W2897539966 date "2019-01-01" @default.
- W2897539966 modified "2023-09-30" @default.
- W2897539966 title "Catalytic partial oxidation of CH4 to syn gas (H2/CO) in presence of N2O over periclase type SiO2@Ni(Mg,Al)O catalyst synthesized by non aqueous route" @default.
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- W2897539966 doi "https://doi.org/10.1016/j.catcom.2018.10.011" @default.
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