Matches in SemOpenAlex for { <https://semopenalex.org/work/W2897555854> ?p ?o ?g. }
- W2897555854 endingPage "16741" @default.
- W2897555854 startingPage "16737" @default.
- W2897555854 abstract "Abstract Non‐alternant, non‐benzenoid π‐conjugated polycyclic hydrocarbons (PHs) are expected to exhibit very different electronic properties from all‐benzenoid PHs. Reported herein are the syntheses and physical properties of four derivatives of two azulene‐fused s‐indacene isomers, the diazuleno[2,1‐a:2′,1′‐g]‐s‐indacene (DAI‐1) and diazuleno[2,1‐a:1′,2′‐h]‐s‐indacene (DAI‐2). The backbone of both isomers contains 28π electrons and is a 7‐5‐5‐6‐5‐5‐7 fused ring system. X‐ray crystallographic analysis, NMR spectra, and theoretical calculations (ACID, NICS) reveal a structure with two aromatic azulene units fused with a central anti‐aromatic s‐indacene moiety. All compounds exhibit open‐shell diradical character and are magnetically active, but the derivatives of DAI‐2 show larger radical character than the respective ones of DAI‐1. Their dications were isolated in crystalline form and all experimental and theoretical analyses disclose a shift of local (anti)aromaticity along the backbone, with two aromatic tropylium rings at the termini." @default.
- W2897555854 created "2018-10-26" @default.
- W2897555854 creator A5002634340 @default.
- W2897555854 creator A5009545229 @default.
- W2897555854 creator A5012283082 @default.
- W2897555854 creator A5022284931 @default.
- W2897555854 creator A5026128903 @default.
- W2897555854 creator A5036621108 @default.
- W2897555854 creator A5042549842 @default.
- W2897555854 creator A5052342599 @default.
- W2897555854 creator A5074550797 @default.
- W2897555854 creator A5082310995 @default.
- W2897555854 date "2018-11-21" @default.
- W2897555854 modified "2023-10-13" @default.
- W2897555854 title "Diazuleno‐ <i>s</i> ‐indacene Diradicaloids: Syntheses, Properties, and Local (anti)Aromaticity Shift from Neutral to Dicationic State" @default.
- W2897555854 cites W1977375172 @default.
- W2897555854 cites W1983196479 @default.
- W2897555854 cites W2002645636 @default.
- W2897555854 cites W2003720958 @default.
- W2897555854 cites W2015106953 @default.
- W2897555854 cites W2018073239 @default.
- W2897555854 cites W2025658931 @default.
- W2897555854 cites W2032003798 @default.
- W2897555854 cites W2058957873 @default.
- W2897555854 cites W2067570011 @default.
- W2897555854 cites W2070005238 @default.
- W2897555854 cites W2079581645 @default.
- W2897555854 cites W2120721552 @default.
- W2897555854 cites W2121170859 @default.
- W2897555854 cites W2139967976 @default.
- W2897555854 cites W2142143791 @default.
- W2897555854 cites W2142199780 @default.
- W2897555854 cites W2150842650 @default.
- W2897555854 cites W2154409806 @default.
- W2897555854 cites W2164048565 @default.
- W2897555854 cites W2166337065 @default.
- W2897555854 cites W2315426500 @default.
- W2897555854 cites W2325567104 @default.
- W2897555854 cites W2413560912 @default.
- W2897555854 cites W2414797637 @default.
- W2897555854 cites W2417002990 @default.
- W2897555854 cites W2553667454 @default.
- W2897555854 cites W2557852966 @default.
- W2897555854 cites W2759804450 @default.
- W2897555854 cites W2764147542 @default.
- W2897555854 cites W2786634294 @default.
- W2897555854 cites W4232146610 @default.
- W2897555854 cites W4247134901 @default.
- W2897555854 cites W4248753675 @default.
- W2897555854 cites W4250408335 @default.
- W2897555854 cites W4252171814 @default.
- W2897555854 cites W4255908707 @default.
- W2897555854 doi "https://doi.org/10.1002/anie.201810220" @default.
- W2897555854 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30311991" @default.
- W2897555854 hasPublicationYear "2018" @default.
- W2897555854 type Work @default.
- W2897555854 sameAs 2897555854 @default.
- W2897555854 citedByCount "65" @default.
- W2897555854 countsByYear W28975558542019 @default.
- W2897555854 countsByYear W28975558542020 @default.
- W2897555854 countsByYear W28975558542021 @default.
- W2897555854 countsByYear W28975558542022 @default.
- W2897555854 countsByYear W28975558542023 @default.
- W2897555854 crossrefType "journal-article" @default.
- W2897555854 hasAuthorship W2897555854A5002634340 @default.
- W2897555854 hasAuthorship W2897555854A5009545229 @default.
- W2897555854 hasAuthorship W2897555854A5012283082 @default.
- W2897555854 hasAuthorship W2897555854A5022284931 @default.
- W2897555854 hasAuthorship W2897555854A5026128903 @default.
- W2897555854 hasAuthorship W2897555854A5036621108 @default.
- W2897555854 hasAuthorship W2897555854A5042549842 @default.
- W2897555854 hasAuthorship W2897555854A5052342599 @default.
- W2897555854 hasAuthorship W2897555854A5074550797 @default.
- W2897555854 hasAuthorship W2897555854A5082310995 @default.
- W2897555854 hasConcept C112613896 @default.
- W2897555854 hasConcept C117633835 @default.
- W2897555854 hasConcept C121332964 @default.
- W2897555854 hasConcept C147597530 @default.
- W2897555854 hasConcept C178790620 @default.
- W2897555854 hasConcept C181500209 @default.
- W2897555854 hasConcept C185544564 @default.
- W2897555854 hasConcept C185592680 @default.
- W2897555854 hasConcept C192386470 @default.
- W2897555854 hasConcept C20362734 @default.
- W2897555854 hasConcept C2776568683 @default.
- W2897555854 hasConcept C2780378348 @default.
- W2897555854 hasConcept C2781203326 @default.
- W2897555854 hasConcept C32909587 @default.
- W2897555854 hasConcept C33062035 @default.
- W2897555854 hasConcept C521977710 @default.
- W2897555854 hasConcept C71240020 @default.
- W2897555854 hasConcept C75473681 @default.
- W2897555854 hasConceptScore W2897555854C112613896 @default.
- W2897555854 hasConceptScore W2897555854C117633835 @default.
- W2897555854 hasConceptScore W2897555854C121332964 @default.
- W2897555854 hasConceptScore W2897555854C147597530 @default.
- W2897555854 hasConceptScore W2897555854C178790620 @default.
- W2897555854 hasConceptScore W2897555854C181500209 @default.