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- W2897556851 abstract "Ion-induced regulation in the body bears an important body control responsibility, making it one of the most important control mechanisms for ion channels. In this work, we use experimental and theoretical methods to mimic the possible regulation process induced by multivalent ions in an artificial calcium-responsive nanochannel (ACRN). Cerium, whose properties are similar to those of calcium, is introduced as the invasive factor. This trivalent cation can lead to a charge inversion of the inner wall of the ACRN and thus change the ion transport state from cation selectivity to anion selectivity. When both Ce3+ and Ca2+ coexist in the solution, they can change the ionic transport behaviors of the channel synergistically. Calcein is used to functionalize the nanochannel to form the ACRN. The change of surface charge is the key reason to regulating the ion transport and is confirmed by theoretical calculation with the Poisson/Nernst–Plank model." @default.
- W2897556851 created "2018-10-26" @default.
- W2897556851 creator A5019858998 @default.
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- W2897556851 date "2018-10-08" @default.
- W2897556851 modified "2023-10-16" @default.
- W2897556851 title "Effect of Trivalent “Calcium-like” Cations on Ionic Transport Behaviors of Artificial Calcium-Responsive Nanochannels" @default.
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- W2897556851 doi "https://doi.org/10.1021/acs.jpcc.8b08662" @default.
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