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- W2897574992 abstract "An operationally convenient and general method for hydroboration of alkenes, aldehydes, and ketones employing Co(acac)3 as a precatalyst is reported. The hydroboration of alkenes in the presence of HBpin, PPh3, and NaOtBu affords good to excellent yields with high Markovnikov selectivity with up to 97:3 branched/linear selectivity. Moreover, Co(acac)3 could be used effectively to hydroborate aldehydes and ketones in the absence of additives under mild reaction conditions. Inter- and intramolecular chemoselective reduction of the aldehyde group took place over the ketone functional group." @default.
- W2897574992 created "2018-10-26" @default.
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- W2897574992 date "2018-10-19" @default.
- W2897574992 modified "2023-09-30" @default.
- W2897574992 title "Cobalt-Catalyzed Hydroboration of Alkenes, Aldehydes, and Ketones" @default.
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- W2897574992 doi "https://doi.org/10.1021/acs.orglett.8b02775" @default.
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