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- W2897579018 abstract "Abstract In order to overcome the disadvantages of low electrical conductivity and pulverization of Co3O4 anode material, a novel Co3O4/nitrogen-doped carbon composite (Co3O4/N-C) was prepared by annealing a cobalt-based metal-organic framework (MOF) precursor. In this Co3O4/N-C composite, the Co3O4 particles are dispersed uniformly in the matrix of the nitrogen-doped carbon with an average diameter of approximately 10 nm and a mass content of 22.6%. This approach has the advantages that first, the dispersed Co3O4 nanoparticles could increase the lithium ions storage capacity and alleviate the electrode pulverization during the lithium ions insertion/extraction processes; second, the nitrogen-doped carbon material could increase the electrical conductivity of the electrode material and meanwhile serve as a buffer to relieve the structure collapse induced by the large volume change. The as-prepared Co3O4/N-C composite maintains a high reversible discharge capacity of 423 mAhg−1 after 100 cycles at the current density of 100 mAg−1, which is 129% times higher than that of the contrastive nitrogen-doped carbon material. Moreover, this strategy was verified to be effective to produce other transition metal oxides/carbon composite for improving the performance of LIBs." @default.
- W2897579018 created "2018-10-26" @default.
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- W2897579018 date "2019-02-01" @default.
- W2897579018 modified "2023-10-14" @default.
- W2897579018 title "Synthesis of Co3O4/nitrogen-doped carbon composite from metal-organic framework as anode for Li-ion battery" @default.
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- W2897579018 doi "https://doi.org/10.1016/j.jallcom.2018.10.129" @default.
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