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- W2897582816 abstract "This paper describes the use of the copper(i)-catalysed azide-alkyne cycloaddition reaction in an active metal template methodology for the synthesis of [2]rotaxanes both in solution and on polymer resins. The use of TentaGel resin beads has allowed the rotaxane functionalised solid supports to be characterized by 1H HR MAS NMR. Whereas previous research in the assembly of interlocked architectures on surfaces are complicated by the concurrent attachment of large proportions of non-interlocked byproducts, in this example over 80% of the functionalization is the desired interlocked rotaxane. The inclusion of zinc metalloporphyrins in the structure of the [2]rotaxane thread allowed the position of the macrocycle to be 'switched' upon the addition of competing base, removal of the metal or appropriate choice of solvent. Investigations into the pseudocooperative effect the mechanical bond has on the metalloporphyrin-macrocycle coordination equilibrium were performed and the associated effective molarity in this [2]rotaxane was calculated to be 120 mM." @default.
- W2897582816 created "2018-10-26" @default.
- W2897582816 creator A5053457312 @default.
- W2897582816 creator A5065772655 @default.
- W2897582816 date "2018-01-01" @default.
- W2897582816 modified "2023-10-13" @default.
- W2897582816 title "Understanding coordination equilibria in solution and gel-phase [2]rotaxanes" @default.
- W2897582816 cites W1965243534 @default.
- W2897582816 cites W1965723279 @default.
- W2897582816 cites W1967263253 @default.
- W2897582816 cites W1972787707 @default.
- W2897582816 cites W1984270952 @default.
- W2897582816 cites W1985492448 @default.
- W2897582816 cites W1986997934 @default.
- W2897582816 cites W1987895204 @default.
- W2897582816 cites W1995319639 @default.
- W2897582816 cites W1997158083 @default.
- W2897582816 cites W1999928835 @default.
- W2897582816 cites W2000913355 @default.
- W2897582816 cites W2002744212 @default.
- W2897582816 cites W2004860401 @default.
- W2897582816 cites W2005274911 @default.
- W2897582816 cites W2006523474 @default.
- W2897582816 cites W2010080185 @default.
- W2897582816 cites W2011115951 @default.
- W2897582816 cites W2017858766 @default.
- W2897582816 cites W2020903929 @default.
- W2897582816 cites W2027609757 @default.
- W2897582816 cites W2038726284 @default.
- W2897582816 cites W2039719857 @default.
- W2897582816 cites W2042425227 @default.
- W2897582816 cites W2043118399 @default.
- W2897582816 cites W2049454569 @default.
- W2897582816 cites W2060996959 @default.
- W2897582816 cites W2063782027 @default.
- W2897582816 cites W2069207112 @default.
- W2897582816 cites W2073541577 @default.
- W2897582816 cites W2086982692 @default.
- W2897582816 cites W2088654906 @default.
- W2897582816 cites W2089218402 @default.
- W2897582816 cites W2089334898 @default.
- W2897582816 cites W2090343482 @default.
- W2897582816 cites W2092652557 @default.
- W2897582816 cites W2093121827 @default.
- W2897582816 cites W2112096267 @default.
- W2897582816 cites W2117040166 @default.
- W2897582816 cites W2117755495 @default.
- W2897582816 cites W2126457908 @default.
- W2897582816 cites W2126933622 @default.
- W2897582816 cites W2127073361 @default.
- W2897582816 cites W2128349080 @default.
- W2897582816 cites W2130202929 @default.
- W2897582816 cites W2130976075 @default.
- W2897582816 cites W2142447890 @default.
- W2897582816 cites W2142599490 @default.
- W2897582816 cites W2142721038 @default.
- W2897582816 cites W2142937972 @default.
- W2897582816 cites W2146621148 @default.
- W2897582816 cites W2147440332 @default.
- W2897582816 cites W2149087612 @default.
- W2897582816 cites W2149164319 @default.
- W2897582816 cites W2151430274 @default.
- W2897582816 cites W2154792664 @default.
- W2897582816 cites W2164458714 @default.
- W2897582816 cites W2165683367 @default.
- W2897582816 cites W2168770797 @default.
- W2897582816 cites W2170810987 @default.
- W2897582816 cites W2170829955 @default.
- W2897582816 cites W2176250702 @default.
- W2897582816 cites W2318586571 @default.
- W2897582816 cites W2323842433 @default.
- W2897582816 cites W2333591613 @default.
- W2897582816 cites W2340838298 @default.
- W2897582816 cites W2512740112 @default.
- W2897582816 cites W2515235874 @default.
- W2897582816 cites W2518893919 @default.
- W2897582816 cites W2535807074 @default.
- W2897582816 cites W2554156354 @default.
- W2897582816 cites W2597727278 @default.
- W2897582816 cites W2601535288 @default.
- W2897582816 cites W2606410283 @default.
- W2897582816 cites W2606645190 @default.
- W2897582816 cites W2609612189 @default.
- W2897582816 cites W2610345777 @default.
- W2897582816 cites W2610592973 @default.
- W2897582816 cites W2742385874 @default.
- W2897582816 cites W2744116498 @default.
- W2897582816 cites W2799161498 @default.
- W2897582816 cites W2950249426 @default.
- W2897582816 cites W4230175933 @default.
- W2897582816 cites W4245503406 @default.
- W2897582816 cites W4250209635 @default.
- W2897582816 cites W4253623049 @default.
- W2897582816 cites W4322388192 @default.
- W2897582816 cites W4361773018 @default.
- W2897582816 cites W1929403725 @default.
- W2897582816 doi "https://doi.org/10.1039/c8ob02304b" @default.
- W2897582816 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30375613" @default.