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• W2897585293 endingPage "18617" @default.
• W2897585293 startingPage "18613" @default.
• W2897585293 abstract "From the reaction of [Nb6 I11 ] with 2-aminoethanol in pyridine the cluster compound [Nb6 (OC2 H4 NH2 )12 ]I3 has been obtained and the single-crystal X-ray structure determined. It represents the first example of a group VB metal cluster compound with hexanuclear, octahedral metal atom core, which carries intra-cluster chelate ligands. With the formation of this unprecedented cluster cation we report for the first time a transformation of a 6-8 to a 6-12 type cluster unit. The formation of the cluster cation goes along with a one-electron oxidation of the cluster starting material. Furthermore, it adds a second entry to the so far very small group of M6 cluster compounds with organic ligands on the inner cluster sites." @default.
• W2897585293 created "2018-10-26" @default.
• W2897585293 creator A5022463035 @default.
• W2897585293 creator A5039350031 @default.
• W2897585293 date "2018-11-20" @default.
• W2897585293 modified "2023-09-25" @default.
• W2897585293 title "A Hexanuclear Niobium Cluster Compound With Intra‐Cluster Chelate Ligands: [Nb₆(OC₂H₄NH₂)₁₂]I₃" @default.
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• W2897585293 doi "https://doi.org/10.1002/chem.201804344" @default.
• W2897585293 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30341819" @default.
• W2897585293 hasPublicationYear "2018" @default.
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