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• W2897589193 abstract "Photo-/ion-induced ionization and dissociation processes are commonly observed for polycyclic aromatic hydrocarbon (PAH) molecules. This work performs theoretical studies of PAHs and their fragments. Molecular dynamics simulations in combination with static quantum chemical calculations reveal that following a single hydrogen atom loss, the fragments, PAH-H, are extremely reactive. They catch a neighbor molecule within picoseconds to form a covalently bonded large molecule regardless of orientations/angles and temperatures. We calculate the infrared spectra of the covalently bonded molecules, which indicate that such species could be the carrier of unidentified infrared emission bands. It also implies that regular PAHs might be less abundant in space than what is expected." @default.
• W2897589193 created "2018-10-26" @default.
• W2897589193 creator A5014658784 @default.
• W2897589193 date "2018-10-18" @default.
• W2897589193 modified "2023-10-18" @default.
• W2897589193 title "Formation of Covalently Bonded Polycyclic Aromatic Hydrocarbons in the Interstellar Medium" @default.
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• W2897589193 doi "https://doi.org/10.3847/1538-4357/aae38f" @default.
• W2897589193 hasPublicationYear "2018" @default.
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